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3A726515493.jsonld | Document
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"title": "Language attitudes in England and Austria : a sociolinguistic investigation into perceptions of high and low-prestige varieties in Manchester and Vienna",
"abstract": "In both Manchester and Vienna, there is much anecdotal evidence about the social implications of one`s spoken language variety. However, the evaluation of a person`s character based on the way they speak might not necessarily be the same in different countries with different languages. If evaluations of a speaker`s social class, professional status and general character change according to the country and language, then in which ways? By applying a very similar methodological framework in each of these cities, this study sets out to examine the extent to which perceptions of a speaker may vary with the social and linguistic context of each urban environment. Many sociolinguistic studies have already investigated how the way we talk influences the perceptions others have of us. The research presented in this book expands on this idea by directly comparing data across two nations with two different languages.",
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3A726780707.jsonld | Document
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"title": "M\u00f6glichkeiten und Grenzen der mikroskopischen Leichenbranduntersuchung",
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"Die Dissertation behandelt Aussagem\u00f6glichkeiten der mikroskopischen (Lichtmikroskopie und Rasterelektronenmikroskopie) Untersuchung am Leichenbrand. Die Hauptziele der Untersuchung sind eine Pr\u00e4zisierung der Bestimmung des biologischen Lebensalters des Individuums sowie die Feststellung m\u00f6glicher Ver\u00e4nderungen durch pathologische Prozesse und ihre Unterscheidung von verbrennungsbedingte Artefakte. Verglichen wurden unterschiedliche pr\u00e4historische Leichenbr\u00e4nde aus verschiedenen Regionen (Ostt\u00fcrkei, Deutschland, Tschechien, Slowakei), von der mesopotamischen Bronzezeit \u00fcber die vorr\u00f6mische Eisenzeit bis in die r\u00f6mische Kaiserzeit. Als Vergleichsmaterial diente eine rezente Population mit bekanntem Sterbealter."
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3A727070037.jsonld | Document
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"title": "An adaptive communication model for mobile agents in highly dynamic networks based on forming flexible regions via swarming behabiour",
"abstract": "In the last decade, mobile agent technology has been considered as one of the most active research fields in computer science. Mobile agents are software agents which run on behalf of their owner to fulfil jobs that have been ordered (ZK02). They have the ability to migrate from location to location in the network, they can temporarily save their work state at the time of migrating and then restore their tasks when arriving at the new location. Their outstanding characteristics are to be autonomous, reactive, opportunistic, and goal-oriented. Those characteristics are suitable for distributed applications, such as resource allocation (TYI99), network management (MT99), remote supervision (CMCV02), e-commerce (BGP05), health care systems (Mor06), to name but a few.",
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<|eot_id|> |
3A727862855.jsonld | Document
### Text: {
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"creator": "Li, Zheng",
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"(classificationName=bk, id=106417525)35.80 - Makromolekulare Chemie",
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"title": "The properties of hydrophobically modified water soluble polymers in water and at surfaces",
"abstract": [
"Poly(glycerol methacrylate); Atom transfer radical polymerization; Semitelechelics; Self-association; Hydrogen bond; Chirality; Self-assembled monolayers; Protein adsorption; Cell adhesion",
"Poly(glycerolmethacrylat); radikalische Polymerisation unter Atomtransfer; Semitelechele; Selbstassoziation; Wasserstoffbr\u00fcckenbindung; Chiralit\u00e4t; selbstorganisierte Monoschichten; Proteinadsorption; Zelladh\u00e4sion",
"Novel poly(glycerol methacrylate) (PGMA)-based hydrophobically modified water soluble semitelechelics have been synthesized by combination of atom transfer radical polymerization (ATRP) and/or copper(I)-catalyzed alkyne-azide cycloaddition reaction. Perfluoroalkyl end capped PGMA exhibits a different association behavior in aqueous solution compared to the corresponding PEO semitelechelic due to the hydrogen bonding effect on PGMA segment. The protein adsorption and cell adhesion as a function of the polymer chirality was investigated on racemic or enantiopure chiral PGMA(rac), PGMA(R), and PGMA(S) self-assembled monolayers (SAMs). Enantiopure SAMs based on PGMA(R) or PGMA(S) show a larger reduction in bovine serum albumin (BSA) adsorption and THP-1 cell adhesion than PGMA(rac)-modified surfaces. The higher water content of SAMs formed by enantiopure PGMA(S) and PGMA(R) compared to PGMA(rac) SAMs is the decisive reason for the reduced BSA adsorption and cell adhesion.",
"Neuartige, auf Poly(glycerolmethacrylat) (PGMA) basierende, hydrophob modifizierte, wasserl\u00f6sliche Semitelechele wurden durch Kombination von radikalischer Polymerisation unter Atomtransfer (ATRP) und/oder Kupfer(I)-katalysierter Alkin/Azid-Cycloadditionsreaktion synthetisiert. Perfluoroalkyl-endst\u00e4ndiges PGMA zeigt aufgrund des Effekts der Wasserstoffbr\u00fcckenbindung am PGMA-Segment ein unterschiedliches Assoziationsverhalten in w\u00e4ssriger L\u00f6sung im Vergleich zu dem entsprechenden PEO-Semitelechel. Die Proteinadsorption und Zelladh\u00e4sion wurde als Funktion der Polymerchiralit\u00e4t an selbstorganisierten Monoschichten (SAMs) von racemisch oder enantiomerenrein chiralem PGMA(rac), PGMA(R) und PGMA(S) untersucht. Enantiomerenreine, auf PGMA(R) oder PGMA(S) basierende SAMs zeigen eine gr\u00f6\u00dfere Reduzierung bei der Adsorption von Rinderserumalbumin (BSA) und bei der Zelladh\u00e4sion von THP-1 als PGMA(rac)-modifizierte Oberfl\u00e4chen. Der im Vergleich zu PGMA(rac)-SAMs h\u00f6here Wassergehalt bei SAMs, die aus enantiomerenreinen PGMA(R) und PGMA(S) aufgebaut sind, ist der entscheidende Grund f\u00fcr die reduzierte BSA-Adsorption und Zelladh\u00e4sion."
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3A728817039.jsonld | Document
### Text: {
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"title": "Fluoreszierendes gel\u00f6stes organisches Material (FDOM) in K\u00fcstenmeeren : Charakterisierung, biogeochemische Prozesse, und die M\u00f6glichkeit der in situ \u00dcberwachung",
"abstract": [
"Marine dissolved organic matter (DOM) is a major player in global biogeochemical cycles. Here, DOM was studied for the first time with optical and molecular methods in a subterranean estuary (STE) and it was compared to a surface estuary, both in Florida, USA. I hypothesized that STEs are important sources of DOM to the coastal ocean. I developed novel statistical tools for multivariate data interpretation. As a main result, I could show that coastal sediments are major sources of DOM to the coastal ocean. In the surface estuary, mixing of fresh- and seawater was the main driver for DOM concentration and composition, while in the STE microbial processing dominated over mixing. By statistically combining the results from ultrahigh-resolution mass spectrometry (Fourier-transform ion cyclotron resonance mass spectrometry, FT-ICR-MS), fluorescence spectroscopy and other chemical water analysis, I identified major DOM sources in the two estuarine systems. Furthermore, I proposed novel optical monitoring tools for in situ continuous monitoring in coastal systems. <engl.>",
"Das gel\u00f6ste organische Material (DOM) der Meere ist eine wichtige Komponente globaler Stoffkreisl\u00e4ufe. In dieser Arbeit wurde zum ersten Mal DOM in einem unterirdischen \u00c4stuar (STE) mit optischen und molekularen Methoden untersucht. Vergleichend wurde zudem ein klassisches \u00c4stuar untersucht, beide Untersuchungsgebiete lagen in Florida (USA). Ich stellte die Hypothese auf, dass STEs wichtige Quellen von DOM in K\u00fcstengebieten sind. Ich entwickelte neuartige statistische Methoden zur multivariaten Dateninterpretation. Als eines der wichtigsten Ergebnisse konnte ich zeigen, dass K\u00fcstensedimente wichtige Quellen von DOM sind. Im klassischen \u00c4stuar waren einfache Mischungsprozesse f\u00fcr die Konzentration und Zusammensetzung von DOM entscheidend, w\u00e4hrend im STE mikrobielle Prozesse \u00fcberwogen. Mit Hilfe statistischer Methoden konnte ich die Ergebnisse von ultrahochaufl\u00f6sender Massenspektrometrie (FT-ICR-MS) mit Fluoreszenzdaten und wasserchemischen Daten kombinieren und den Ursprung des DOM in den zwei \u00c4stuaren identifizieren. Des Weiteren habe ich zur Entwicklung neuer optische Methoden f\u00fcr die automatisierte \u00dcberwachung beigetragen. <dt.>"
],
"alternative": "Fluorescent dissolved organic matter (FDOM) in the coastal ocean",
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<|eot_id|> |
3A729348083.jsonld | Document
### Text: {
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"title": "Least-squares finite element methods for coupled generalized Newtonian Stokes-Darcy flow",
"abstract": "Least-squares finite element method, non-Newtonian fluids, Beavers-Joseph-Saffman condition, a-posteriori error estimator, adaptive refinement, Gau\u00df-Newton method. - Least-squares Finite-Element-Methode, nichtnewtonsche Fluide, Beavers-Joseph-Saffman Bedingung, a-posteriori Fehlersch\u00e4tzer, adaptive Verfeinerung, Gau\u00df-Newton Verfahren",
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<|eot_id|> |
3A729515060.jsonld | Document
### Text: {
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"sameAs": "Stickstoffd\u00fcngung"
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{
"@id": "gnd:4065287-7",
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"Humbeck, Klaus",
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"(classificationName=linseach:mapping)bio",
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"title": "Iron and zinc translocation from senescent leaves to grains of wheat (Triticum aestivum cv. Akteur)in response to nitrogen fertilization and citric acid application",
"abstract": [
"In plant seeds, the micronutrients Fe and Zn are required to sustain the early development of seedlings. A large part of the Fe and Zn in the seeds derives from retranslocation from senescing leaves or stems. Nitrogen nutrition has been reported to play an important role in micronutrient retranslocation to grains by stimulating the synthesis of Fe chelators like nicotianamine and phytosiderophores. The present study assessed the effect of different N fertilizer forms on leaf senescence and on micronutrient accumulation in wheat grains (Triticum aestivum cv. Akteur) under field conditions in two consecutive years. Flag leaf senescence was delayed by N fertilization, and in both field experiments the supply of ammonium after anthesis resulted in higher Fe and Zn contents in the grains. Nicotianamine levels increased in leaves and leaf exudates, whereas phytosiderophore concentrations were less responsive to N treatments. To enhance Fe and Zn mobilization, citric acid was sprayed onto senescing leaves of wheat. In N-fertilized plants citric acid application did not increase Fe and Zn accumulation in grains. However, in non-fertilized plants citric acid application increased Fe and Zn remobilization and led to significantly elevated Fe contents in the grains. The results of the present study indicate that N fertilization can improve the fortification of wheat grains with Fe and Zn, in particular when the different effects of fertilizer N forms are respected, while citric acid application could not be proven efficient to increase Fe and Zn accumulation in grains.",
"Triticum aestivum; nicotianamine; phytosiderophore; senescence; chelator; citric acid; micronutrients; nitrate; ammonium; urea",
"Triticum aestivum; Ncotianamin; Phytosiderophore; Seneszenz; Chelatoren; Zitronens\u00e4ure; Mikron\u00e4hrstoffe; Nitrat; Ammonium; Harnstoff",
"In Getreidesamen werden die Mikron\u00e4hrstoffe Fe und Zn f\u00fcr die fr\u00fche Entwicklung des Keimlings ben\u00f6tigt. Ein gro\u00dfer Teil dieser Mikron\u00e4hrstoffe stammt aus der Retranslokation von Fe und Zn aus seneszierenden Bl\u00e4ttern. F\u00fcr die Retranslokation von Fe und Zn spielt die Stickstoffern\u00e4hrung eine wichtige Rolle, da Stickstoff (N) die Synthese von N-haltigen Schwermetall-Chelatoren wie Nicotianamin und Phytosiderophoren stimuliert. Die vorliegende Arbeit hatte zum Ziel, den Einfluss unterschiedlicher N-D\u00fcngemittelformen auf die Blattseneszenz und Mikron\u00e4hrstoff-anreicherung in Weizenk\u00f6rnern (Triticum aestivum cv. Akteur) unter Feldbedingungen zu untersuchen. Es zeigte sich, dass die Seneszenz der Fahnenbl\u00e4tter durch N-D\u00fcngung verz\u00f6gert wurde und dass v.a. eine D\u00fcngung mit Ammonium nach der Bl\u00fcte zu erh\u00f6hten Fe- und Zn-Gehalten in den K\u00f6rnern f\u00fchrte. Stickstoffapplikation f\u00fchrte auch zu erh\u00f6hten Nicotianamingehalten in Bl\u00e4ttern und Blattexudaten, wogegen die Phytosiderophorkonzentrationen weit weniger beeinflusst wurden. Um die Fe- und Zn-Retranslokation zu erh\u00f6hen, wurde in einem weiteren Versuch Zitronens\u00e4ure auf seneszierende Bl\u00e4tter von Freilandweizen gespr\u00fcht. In N-ged\u00fcngten Pflanzen ver\u00e4nderte die Blattapplikation von Zitronens\u00e4ure allerdings nicht die Fe- und Zn-Anreicherung in den Samen, wogegen in unged\u00fcngten Pflanzen die Fe- und Zn-Gehalte in den Samen signifikant anstiegen. Die Ergebnisse dieser Arbeit zeigen, dass N-D\u00fcngung die Fe- und Zn-Anreicherung in Weizensamen verbessern kann und zwar besonders dann, wenn unterschiedliche Effekte der N-D\u00fcngemittelform ber\u00fccksichtigt werden, w\u00e4hrend f\u00fcr eine Blattapplikation von Zitronens\u00e4ure keine positive Wirkung auf die Retranslokation von Fe oder Zn nachgewiesen werden konnte."
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<|eot_id|> |
3A731604202.jsonld | Document
### Text: {
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"title": "Ein effizienter Ansatz zur \u00dcbersetzung zwischen Service-Protokollen durch die Modellierung von Verhaltensunterschieden",
"abstract": [
"For developers, the integration of service protocols into applications is still a tedious and time-consuming task. This problem can be solved by programming software that converts one protocol to another. Thereby, design-patterns, data transformation technologies or manual coding are used to integrate these protocols. Also, several model-driven solutions can be used that focus on the formal description of protocols to automatically generate converters. This thesis describes a model-driven approach that has been designed to convert service protocols into each other. The approach focuses on the modeling of the differences between protocols. The differences in the communication behavior are described using patterns, while the state of a service can be described using decision trees. The evaluation contains an analysis of the processing times of the patterns as well as a comparison with other model-driven approaches. <engl.>",
"Die Integration von Service-Protokollen in Applikationen ist noch immer eine aufw\u00e4ndige und zeitintensive Aufgabe f\u00fcr Entwickler. Bei softwaretechnischen L\u00f6sungen wird versucht, dieses Problem mittels Design-Pattern, Datentransformationstechnologien oder manueller Programmierung zu l\u00f6sen. Modellgetriebene Ans\u00e4tze konzentrieren sich dagegen auf eine formale Beschreibung der Protokolle, um daraus automatisiert Konverter zu generieren. In dieser Arbeit wird ein neues Modellierungsverfahren vorgestellt, das speziell f\u00fcr die Konvertierung von Service-Protokollen entwickelt wurde. Der Ansatz konzentriert sich auf die Modellierung von Protokollunterschieden und erlaubt die Beschreibung von \u00c4nderungen des Kommunikationsverhaltens mittels Mustern. Dar\u00fcber hinaus k\u00f6nnen Zust\u00e4nde durch Entscheidungsb\u00e4ume abgebildet werden. Neben der Evaluation der Verarbeitungszeiten wird in der Arbeit auch der Aufwand des Modellierungsansatzes gegen eine softwaretechnische L\u00f6sung abgeglichen. <dt.>"
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<|eot_id|> |
3A731846079.jsonld | Document
### Text: {
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"sameAs": "Leuthold, Martin"
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{
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"sameAs": "Polyallylamine"
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"(classificationName=ddc-dbn)540",
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"(classificationName=linseach:mapping)che",
"(classificationName=ddc-dbn)610"
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"title": "Characterization of membrane adsorbers for contaminant removal",
"abstract": "High-throughput screening, contaminant removal, salt-tolerant membrane adsorber. - Hochdurchsatzscreening, Kontaminantenentfernung, salztolerante Membranadsorber",
"contributor": "Technische Informationsbibliothek (TIB)",
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3A732204267.jsonld | Document
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3A735493294.jsonld | Document
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3A736219099.jsonld | Document
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3A738503444.jsonld | Document
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<|eot_id|> |
3A743637429.jsonld | Document
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<|eot_id|> |
3A744897823.jsonld | Document
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3A74587973X.jsonld | Document
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<|eot_id|> |
3A74778423X.jsonld | Document
### Text: {
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<|eot_id|> |
3A749374004.jsonld | Document
### Text: {
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"title": "Seismic attenuation system (AEI-SAS) for the AEI 10 m prototype",
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<|eot_id|> |
3A750586516.jsonld | Document
### Text: {
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<|eot_id|> |
3A75237303X.jsonld | Document
### Text: {
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"title": "Antibacterial Mg-Ag biodegradable alloys",
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<|eot_id|> |
3A756452341.jsonld | Document
### Text: {
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"title": "Synthese und Evaluierung neuartiger Triterpenderivate",
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"Betulinic acid and Glycyrrhetinic acid are of great interest in pharmacological and chemical research because of their great potential for treating several diseases including HIV, herpes and cancer. Both triterpenes are wide-spread in plant kingdom and showed cytotoxic activity against several cancer cell lines by triggering apoptosis. Betulinic acid showed a selective cytotoxicitiy for melanoma cells in an animal model. Because of no acute or chronic side effects even at doses of 500 mg/kg, betulinic acid prevails as a potent alternative in chemotherapeutic therapy, which is currently researched in clinical trials. The subject of this work is synthesis and evaluation of novel derivates of betulinic acid and glycyrrhetinic acid bearing a carbon-carbon triple bond. The prepared alkynol and alkynketone derivates were evaluated by using a SRB assay. Several alkyne derivates showed increased cytotoxic behavior against nine cancer cell lines with IC50 > 1 \u03bcM. Additional several triazols and propargyl amines were gained from alkynyl derivates and showed good cytotoxic activity. Further assays like AO/EP, trypan blue, annixin-V , investigation of cell cycle and DNA laddering experiments suggest that alkynyl derivates trigger apoptosis in cancer cell lines.",
"Betulin; Betulins\u00e4ure; Glycyrrhetins\u00e4ure; Propargylamine; Aminomethylierung; 1,2,3-Triazol; Klick-Rekation; Alkin; Mannich; Apoptose; SRB-Assay",
"betulin; betulinic acid; glycyrrhetinic acid; propargyl amin; 1,2,3-triazol; Click-reaction; alkynyl; Mannich; apoptosis; SRB-assay",
"Triterpene sind durch ihre vielf\u00e4ltigen pharmakologischen Eigenschaften ins Interesse der chemisch pharmazeutischen Forschung ger\u00fcckt. Betulin- und Glycyrrhetins\u00e4ure sind beispielhafte Naturstoffe mit antiviralen, antiinflammatorischen und antikanzerogenen Potential. Die m\u00f6gliche apoptotische Wirkungsweise macht sie zu wertvollen Alternativen in der Krebsmedizin. In der vorliegenden Arbeit wird der Einfluss von Alkinsubstituenten auf das zytotoxische Verhalten dieser Triterpene untersucht. Die synthetisierten Alkinole und Alkinketone wurden mit Hilfe des SRB-Assay`s auf ihre zytotoxischen Aktivit\u00e4ten analysiert wurden. Dabei wurde gezeigt, dass mit Alkinderivaten von Betulin und Glycyrrhetins\u00e4ure im Vergleich mit den Referenzsubstanzen \u00fcbereinstimmende Wachstumsraten zu erzielen sind. Neun Alkinderivate \u00fcbertreffen die Aktivit\u00e4ten der Referenzen mit IC50-Werten teilweise unter 1 \u03bcM deutlich. Synthetisierte Triazol- und Propargylderivate zeigen ebenfalls gesteigertes zytotoxisches Potential. Ausgew\u00e4hlte Verbindungen wurden zudem mit dem AO/PI- bzw. AO/EB-Assay, dem Trypan-blue-Assay, dem Annexin-V-Assays sowie DNA-Laddering und Zellzyklusanalysen hinsichtlich ihrer apoptotischer Wirkweise untersucht."
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<|eot_id|> |
3A756792703.jsonld | Document
### Text: {
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"Die Termintreue ist eine der wichtigsten logistischen Zielgr\u00f6\u00dfen in der Produktion. Vielen Unternehmen f\u00e4llt es jedoch schwer, die Termintreue systematisch zu steuern. Ob eine Fertigung ihre Auftr\u00e4ge termintreu fertigstellt, h\u00e4ngt vom R\u00fcckstand und der Reihenfolgeabweichung ab. Die in dieser Arbeit entwickelte Modellierung der Termintreue in Abh\u00e4ngigkeit von ihren Einflussgr\u00f6\u00dfen deckt die Ursachen mangelhafter Termintreue auf und erm\u00f6glicht zielgerichtete Ver\u00e4nderungen zur ihrer Verbesserung."
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<|eot_id|> |
3A757176925.jsonld | Document
### Text: {
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"title": "Amino cellulose sulfate : synthesis, characterization and physicochemical behavior",
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<|eot_id|> |
3A766472213.jsonld | Document
### Text: {
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"title": "Noise traders in financial markets",
"abstract": "The dissertation focuses on noise traders in financial markets. The first part considers a Rational Expectations equilibrium (REE) model based an Hellwig (1980) and Grossman ans Stiglitz (1980). The aim of this part is to analyze the performance of noise traders by considering expected final wealth. The second part of the dissertation presents an extended version of Arnold and Brunner (2012) ...",
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<|eot_id|> |
3A766574881.jsonld | Document
### Text: {
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"sameAs": "Brinkmeyer, Malte"
},
{
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{
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"title": "Polynomial supertree methods in phylogenomics : algorithms, simulations and software",
"abstract": "One of the objectives in modern biology, especially phylogenetics, is to build larger clades of the Tree of Life. Large-scale phylogenetic analysis involves several serious challenges. The aim of this thesis is to contribute to some of the open problems in this context. In computational phylogenetics, supertree methods provide a way to reconstruct larger clades of the Tree of Life. We present a novel polynomial time approach for the computation of supertrees called FlipCut supertree. Our method combines the computation of minimum cuts from graph-based methods with a matrix representation method, namely Minimum Flip Supertrees. Here, the input trees are encoded in a 0/1/?-matrix. We present a heuristic to search for a minimum set of 0/1-flips such that the resulting matrix admits a directed perfect phylogeny. In contrast to other polynomial time approaches, our results can be interpreted in the sense that we try to minimize a global objective function, namely the number of flips in the input matrix. We extend our approach by using edge weights to weight the columns of the 0/1/?-matrix. In order to compare our new FlipCut supertree method with other recent polynomial supertree methods and matrix representation methods, we present a large scale simulation study using two different data sets. Our findings illustrate the trade-off between accuracy and running time in supertree construction, as well as the pros and cons of different supertree approaches. Furthermore, we present EPoS, a modular software framework for phylogenetic analysis and visualization. It fills the gap between command line-based algorithmic packages and visual tools without sufficient support for computational methods. By combining a powerful graphical user interface with a plugin system that allows simple integration of new algorithms, visualizations and data structures, we created a framework that is easy to use, to extend and that covers all important steps of a phylogenetic analysis.",
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<|eot_id|> |
3A766692604.jsonld | Document
### Text: {
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<|eot_id|> |
3A767010213.jsonld | Document
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3A76985267X.jsonld | Document
### Text: {
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"Als FeMFI werden Materialien bezeichnet, bei denen Eisenspezies entweder im Porengef\u00fcge des Zeolithen ZSM-5 auf Kationenpl\u00e4tzen fixiert oder als Gitteratome Aluminium ersetzen. Es gelang FeMFI-Katalysatoren unter Anwendung einer modifizierten hydrothermalen Synthese nach A. Br\u00fcckner zu pr\u00e4parieren und die Einwirkung verschiedener Syntheseparameter auf das Erscheinungsbild der Materialien zu verifizieren. Neben den \u00fcblich, zur Charakterisierung von zeolithischen Katalysatoren eingesetzten Methoden wie REM, XRD und IR kamen solche Methoden zum Einsatz, die in der Lage sind die verschiedenen Eisenspezies zu unterscheiden und qualitativ und quantitativ zu identifizieren (M\u00f6\u00dfbauer-Spektroskopie, ICP-MS). Die Nachbehandlung bestimmter FeMFI-Katalysatoren bei hohen Temperaturen kann zur teilweisen Zersetzung vorhandener Eisenpartikel f\u00fchren. Als weiteres Ziel sollte ein m\u00f6glichst geschlossener, krustenartiger auf der Oberfl\u00e4che von strukturierten Stahlgeweben erzeugt werden. Es wurde best\u00e4tigt, dass die in situ FeMFI-Synthese f\u00fcr die Herstellung von Kompositkatalysatoren geeignet ist. <dt.>"
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<|eot_id|> |
3A772189145.jsonld | Document
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<|eot_id|> |
3A773010610.jsonld | Document
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<|eot_id|> |
3A774525681.jsonld | Document
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"title": "Classical solutions for stabilized periodic Hele-Shaw flows with a free surface",
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3A774621508.jsonld | Document
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<|eot_id|> |
3A776205110.jsonld | Document
### Text: {
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<|eot_id|> |
3A776435566.jsonld | Document
### Text: {
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<|eot_id|> |
3A777061392.jsonld | Document
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<|eot_id|> |
3A777839563.jsonld | Document
### Text: {
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"title": "Arsenic and antimony in the environment : release and possible immobilization mechanisms",
"abstract": "This thesis is dedicated to the release and immobilization of As5+ and Sb5+ in contaminated geomaterials. Although the physical properties and chemical composition of the contaminated materials vary widely, the mechanisms, which control the fate of the contaminants are supposedly similar. In order to understand these mechanisms, I carried out a mineralogical and geochemical investigation of a soil, which was mixed with contaminated As-rich ash waste. With techniques including powder-PXRD, ICP-MS, sequential extractions, EMPA and synchrotron based \u00b5-XRD and XANES, the carriers of As5+ in the fresh ash waste and soil-ash mixtures were identified and characterized. Glass particles and unburned coal particles with veinlets of As-rich calcite are the main carriers of As5+. In the soil-ash mixtures, the soluble As5+ containing phases of the ash-waste almost completely disappeared and As5+ migrated into the soil components, presumably consisting of iron oxides. In the following study, the immobilization of As5+ by iron oxides in the context of As5+ incorporation in hematite was investigated. As5+-ferrihydrite was transformed to hematite and examined by ICP-MS, powder-XRD, SEM, TEM, and EXAFS spectroscopy. The results show that As5+ can be incorporated into hematite with concentrations of 1.9 wt%. This novel immobilization mechanism encouraged me to investigate the possibility of Sb5+ incorporation into iron oxides in a subsequent study. Ferrihydrite was doped with different concentrations of Sb5+, As5+, and P5+ and transformed to more-well crystalline products. The transformation products were analyzed and characterized by ICP-MS, PXRD, SEM and TEM. The results show that Sb5+ directly controls the outcome of the ferrihydrite transformation and therefore the transformation products. These transformation products contain Sb5+ with up to 14 wt.%, exceeding an exclusive adsorption mechanism by far, suggesting structural incorporation of Sb5+ into the iron oxides.",
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<|eot_id|> |
3A779252977.jsonld | Document
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"title": "Impact of aquifer heterogeneity on subsurface flow and salt transport at different scales : from a method determine parameters of heterogeneous permeability at local scale to a large-scale model for the sedimentary basin of Thuringia",
"abstract": "More than 70% of the German population rely on groundwater as their daily drinking water supply. Hence, the understanding of processes like fluid flow and solute transport in porous media are of broad relevance. However, subsurface hydrology faces two problems. On the one hand, information about the subsurface structure and hydraulic properties is scarce. On the other hand, many aquifer parameters like the permeability which controls the flow velocity, are heterogeneously distributed in space. This thesis is dedicated to the question of how aquifer heterogeneity impacts on subsurface flow and transport processes at different scales. We first present a large-scale numerical model of the Thuringian basin in order to investigate the mechanisms of saltwater transport. The results underline the fact that permeability and its heterogeneous spatial distribution are decisive factors for the evolving flow and salt patterns. Our results show that the correlation structure and the degree of heterogeneity (variance) impact significantly on the amount of dissolved salt and the location where salt reaches near-surface regions. Thermally induced convection is not present. However, variations in fluid density due to dissolved salt can lead to significant changes in the distribution and amount of salt in the Thuringian Basin. We further focus on a method to determine the statistical parameters which describe the heterogeneous spatial distribution of permeability by analyzing well flow at local scale. This is of interest, because pumping tests are a widely used tool to infer on porous medium characteristics. We derive an analytical solution which describes the drawdown of a steady state pumping test in 3D heterogeneous anisotropic media by making use of upscaling theory. By combining the analytical solution with an inverse estimation strategy we determine the statistical parameters, like mean permeability, variance and correlation length from on-site pumping tests.",
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<|eot_id|> |
3A780183738.jsonld | Document
### Text: {
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"Many large virtual 3D scenes are not structured evenly, for example because they exhibit a highly varying density distribution of their polygons. For such heterogeneous data, there is no single algorithm that constantly performs well with any type of scene and that is able to render the scene at each position fast with the same high image quality. For a small set of scenes, this situation can be improved, if an experienced user is able to manually assign different rendering algorithms to particular parts of the scene. We introduce the Multi- Algorithm-Rendering method which automatically deploys different rendering algorithms simultaneously for a broad range of scene types. The method divides the scene into suitable subregions and measures the behavior of the different algorithms for each region in a preprocessing step. During runtime, this data is utilized to compute an estimate for the quality and running time of the available rendering algorithms from the observers point of view. By solving an optimizing problem embedded in a control cycle, the image quality can be optimized by the appropriate assignment of algorithms to regions, while keeping the achieved frame rate almost constant. In an experimental evaluation, we compare our methods running time and image quality with that of standard rendering algorithms.",
"Viele gro\u00dfe virtuelle 3-D-Szenen sind nicht gleichm\u00e4\u00dfig strukturiert, z. B. weil sie eine stark schwankende Dichteverteilung der Geometrie aufweisen. F\u00fcr solche ungleichm\u00e4\u00dfig strukturierten Szenen gibt es keinen Algorithmus, der an allen Betrachterpositionen gut funktioniert, also f\u00fcr beliebige Positionen ein Bild mit guter Qualit\u00e4t in annehmbarer Zeit darstellt. F\u00fcr eine kleine Teilmenge dieser Szenen kann die Situation verbessert werden, indem ein erfahrener Benutzer per Hand f\u00fcr einzelne Bereiche einer Szene entscheidet, mit welchem Algorithmus diese dargestellt werden. In dieser Arbeit wird ein Verfahren vorgestellt, welches automatisch unterschiedliche Algorithmen gleichm\u00e4\u00dfig strukturierten Bereichen einer Szene zuordnet. Die Methode teilt daf\u00fcr die Szene in brauchbare Bereiche auf und misst das Verhalten unterschiedlicher Algorithmen auf diesen Bereichen in einem Vorberechnungsschritt. Zur Laufzeit werden diese Daten dann genutzt, um eine Vorhersage f\u00fcr die Laufzeit und den entstehenden Bildfehler der einzelnen Algorithmen auf den Bereichen der Szene abh\u00e4ngig von der Position des Betrachters zu erhalten. Mittels L\u00f6sens eines in einen Regelkreis eingebetteten Optimierungsproblems kann dann die Bildqualit\u00e4t durch eine geschickte Zuordnung von Algorithmen zu Bereichen bei nahezu konstanter Bildrate optimiert werden. In einer experimentellen Evaluierung werden sowohl Laufzeit als auch Bildqualit\u00e4t unserer Methode mit denen von Standardverfahren verglichen."
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<|eot_id|> |
3A781214912.jsonld | Document
### Text: {
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"title": "Infrarot- und Massenspektrometer-System f\u00fcr die dynamische Messung von Motorabgasen",
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"Due to growing individual transport in industrial countries and associated increase in pollutant emissions, legislature toughens emission standards regularly. Automakers are therefor challenged to develop ever more efficient low-emission vehicles to take account of the public climate debate and effects of pollutants on humans and nature. Conventional exhaust gas measurement systems are limited when it comes to measuring gases other than O2, CO2, CO, NOX and total-HC or when high measurement frequencies are of the essence to resolve transient processes. Additional specialized single component measurement systems increase the already high complexity of conventional exhaust emission measurement devices. Topic of this work was the study of all aspects of a mobile, versatile and dynamic exhaust gas measurement system, which integrates the multi component measurement systems mass spectrometer and Fourier-Transform infrared spectrometer. Analyzers were specifically modified and optimized for this application, a common sampling system was designed, and a corresponding software structure was realized. Methods were researched for the optimal adjustment of the system to different applications and for increasing system stability as well as minimizing calibration effort by measuring combustion products like CO2 and H2O and other components with both analyzers in parallel. Additionally Argon is used as some kind of internal standard to adjust and stabilize the mass spectrometer. Measurements in the laboratory and on gasoline and diesel engines show, that limited and non-limited as well as other exhaust gas components can be detected in concentrations down to 1 ppm and with up to 20 Hz. As exemplary applications the measurement of all main exhaust gas components, the differentiation of hydro carbons, the behavior of nitrogen oxides and ammonia on a SCR catalytic converter, the detection of hydrogen in gasoline engine exhaust and the determination of exhaust mass flow rate using Helium as tracer gas are demonstrated. This work shows the advantages of the hybrid measurement system over conventional exhaust emission measurement devices. Higher measurement frequency and much broader spectrum of detectable gas components open a very wide field of application. Lower calibration effort and compact design allow an efficient operation on a regular basis. It can be advantageous deployed to solve current and future problems in exhaust gas measurement as well as outside this field of application.",
"Um der Zunahme von Schadstoffemissionen durch den stetig wachsenden motorisierten Individualverkehr in Industrienationen entgegenzuwirken, werden seitens der Gesetzgeber Emissionsgrenzwerte regelm\u00e4\u00dfig versch\u00e4rft. Automobilhersteller sind daher gefordert, immer effizientere und schadstoff\u00e4rmere Fahrzeuge zu entwickeln. Konventionelle Abgasmesstechniken sto\u00dfen bei aktuellen Fragestellungen an ihre Grenze, wenn neben O2, CO2, CO, NOX und Gesamt-HC weitere Stoffe gemessen, oder mit einer hohen Messfrequenz transiente Vorg\u00e4nge abgebildet werden m\u00fcssen. Durch den Einsatz zus\u00e4tzlicher, spezieller Einkomponenten-Messsysteme wird die bereits hohe Komplexit\u00e4t der konventionellen Abgasmessanlagen weiter gesteigert. Gegenstand dieser Arbeit war die Untersuchung ger\u00e4tetechnischer und methodischer Aspekte eines mobilen, universellen und dynamischen Abgasmesssystems, das die bei- den an Pr\u00fcfst\u00e4nden etablierten Mehrkomponenten-Messsysteme Massenspektrometer und Fourier-Transform-Infrarot-Spektrometer integriert. Dazu wurden Analysatoren speziell f\u00fcr diese Anwendung modifiziert und optimiert, eine gemeinsame Probenahme ausgelegt und eine entsprechende Softwarestruktur realisiert. Es sind Methoden untersucht worden, mit denen das hybride Messsystem optimal f\u00fcr unterschiedliche Anwendungen einzustellen ist, durch parallele Messungen der Verbrennungsprodukte CO2 und H2O sowie weiterer Stoffe die Systemstabilit\u00e4t gesteigert und der Kalibrieraufwand minimiert wird. Argon kann dabei als eine Art interner Standard zur Einstellung und Stabilisierung des Massenspektrometers genutzt werden. Messungen im Labor sowie an Otto- und Dieselmotoren zeigen, dass limitierte und nicht- limitierte Schadstoffe sowie weitere Abgaskomponenten ab Konzentrationen von ca. 1 ppm mit bis zu 20 Hz gemessen werden k\u00f6nnen. Als beispielhafte Anwendungen werden die Messung der Abgas-Hauptkomponenten, die Differenzierung von Kohlenwasserstoffen, das Verhalten von Stickoxiden und Ammoniak am SCR-Katalysator, der Nachweis von Wasserstoff im Ottoabgas sowie die Bestimmung des Abgasmassenstroms mittels Helium als Tracergas aufgezeigt. Mit dieser Arbeit wird gezeigt, dass das hybride Abgasmesssystem viele Vorz\u00fcge gegen\u00fcber der konventionellen Abgasmesstechnik hat. Die h\u00f6here Messfrequenz sowie das viel breitere Spektrum messbarer Stoffe er\u00f6ffnen einen sehr gro\u00dfen Einsatzbereich, und der geringere Kalibrieraufwand sowie die kompakte Bauweise erlauben einen effizienten Routinebetrieb. Es kann f\u00fcr aktuelle und zuk\u00fcnftige Fragestellungen der Abgasmesstechnik, aber auch au\u00dferhalb dieses Anwendungsgebiets gewinnbringend eingesetzt werden."
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<|eot_id|> |
3A782265634.jsonld | Document
### Text: {
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"contributor": [
"Igalson, Ma\u0142gorzata",
"Parisi, J\u00fcrgen"
],
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"title": "Impact of gallium on the defect landscape of sulfur-based chalcopyrite solar cells",
"abstract": [
"The open circuit voltag of solar cells based on Cu(In,Ga)S2 is limited by recombination losses via interface defect states. An increase of the open circuit voltage can be achieved by increasing the Ga content. However, little is known about the effect of Ga on the energy bands in sulfur-based chalcopyrites. In this work Cu(In,Ga)S2 solar cells with different Ga depth profiles are investigated by means of electro-optical methods with regard to the influence of Ga on the device and defect parameters. The results provide information about the influence of Ga on the energy bands of Cu(In,Ga)S2 solar cells. Furthermore, the characteristics of signatures evaluated by means of thermal admittance spechtroscopy are compared to those of the signatures N1 and N2 that are known from Cu(In,Ga)Se2 solar cells. This allows for further classification of the observed signatures. <engl.>",
"Die Leerlaufspannung von Solarzellen basierend auf Cu(In,Ga)S2 wird durch Rekombinationsverluste \u00fcber Grenzfl\u00e4chendefekte limitiert. Erh\u00f6hte Werte f\u00fcr die Leerlaufspannung lassen sich durch erh\u00f6hte Ga-Konzentrationen erzielen. Dabei ist \u00fcber den Einfluss von Ga auf die Energieb\u00e4nder in Schwefel-basierten Chalcopyriten bisher wenig bekannt. In dieser Arbeit werden Cu(In,Ga)S2 Solarzellen mit unterschiedlichen Ga-Tiefenprofilen in der Absorberschicht mit Hinblick auf den Einfluss von Ga auf Solarzellenparameter und Defekteigenschaften mit Hilfe elektro-optischer Methoden untersucht. Die ermittelten Zusammenh\u00e4nge geben Aufschluss auf den Einfluss von Ga auf die Energieb\u00e4nder in Cu(In,Ga)S2 Solarzellen. Dar\u00fcber hinaus werden die Eigenschaften der mittels Admittanzspektroskopie nachgewiesenen Signaturen mit den Charakteristika der in Cu(In,Ga)Se2 Solarzellen auftretenden Signaturen N1 und N2 verglichen. Auf diese Weise k\u00f6nnen die beobachteten Signaturen weiter klassifiziert werden. <dt.>"
],
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<|eot_id|> |
3A782266126.jsonld | Document
### Text: {
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"title": "Sinnvolle Supervision : Sinndimensionen der Supervisionsliteratur im Dialog mit dem Sinnverst\u00e4ndnis H.-E. Hengstenbergs",
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"Supervision is assumed to be a meaningful form of counselling, which assists in finding meaning in one\u2019s work. This statement is examined through an analysis of relevant literature. The first part of the thesis explores the concept of meaningfulness on the basis of six categories and developes the understanding of supervision. The second part provides a detailed account of current thinking on the topic, and describes further aspects of meaning and sense in supervision. In the third part, Hans-Eduard Hengstenberg\u2019s theory of meaning is presented and applied to supervision. Besides a structure comprised of different elements of meaning and sense, it provides the definition of a criterion for meaningfullness. In the final part the results are compared, discussed and made fruitful for practical application. Thus supervision can help to develop a general competency to deal with questions of meaning, for example in the knowledge of different understandings of sense, a clear distinction between meaningfulness and utility and the definition of criteria for meaningfulness. <engl.>",
"Supervision gilt als sinnvolle Beratungsform, die hilft Arbeit sinnvoll zu gestalten. Diese Annahmen werden mit Hilfe einer Literaturanalyse von 34 deutschsprachigen Ver\u00f6ffentlichungen zu Supervision und Sinn untersucht. Der erste Teil der Dissertation erl\u00e4utert den Sinnbegriff an Hand von sechs Sinnkategorien und leitet Supervision theoretisch her. Im zweiten Teil erm\u00f6glicht die Literaturanalyse eine detaillierte Bestandsaufnahme zum Thema, wodurch weitere Sinnaspekte deutlich werden. Im dritten Teil wird die Sinntheorie Hans-Eduard Hengstenbergs vorgestellt und auf Supervision angewandt. Neben einer klaren Struktur aus unterschiedlichen Sinnelementen bietet sie die Definition eines Sinnkriteriums. Im letzten Teil werden die Ergebnisse zusammengef\u00fchrt, wesentliche Erkenntnisse diskutiert und f\u00fcr die Praxis fruchtbar gemacht. So kann Supervision dazu beitragen, eine allgemeine Sinnkompetenz zu entwickeln, in dem z.B. das eigene und fremde Sinnverst\u00e4ndnisse bekannt sind, sauber zwischen Sinn und Nutzen unterschieden wird und Sinnkriterien klar definiert werden. <dt.>"
],
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<|eot_id|> |
3A782351085.jsonld | Document
### Text: {
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"Geschichte 1990-",
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"title": "\"Erz\u00e4hlte\" Musik in der Gegenwartsliteratur : Untersuchungen zu Treichel, Krausser, Mei\u00dfner und Goetz",
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"Zusammenfassung: The dissertation deals with the way of adapting music in contemporary German novels from an interdisciplinary and intermedial perspective",
"Zusammenfassung: Die Dissertation setzt sich aus interdisziplin\u00e4rer wie intermedialer Perspektive damit auseinander, wie erz\u00e4hlliterarische Texte in der j\u00fcngsten Vergangenheit Musik adaptieren. Im Zentrum steht dabei die Frage, wie es mittels verschiedener literarischer Strategien (Metaphorisierung, Strukturanalogien, verbal music etc.) gelingt, der prinzipiell nicht-semantischen und somit bedeutungskontingenten Musik Bedeutung zuzuschreiben. Diese Semantisierungsprozesse schlie\u00dfen zum einen an eine \u00fcber 200 Jahre alte Tradition der \u201aMusikalisierung\u2018 von Literatur durch Verbalisierung an. In Erz\u00e4hltexten, die sich auf sogenannte klassische beziehungsweise E-Musik konzentrieren, steht daher der parodistische oder affirmative Umgang mit der Tradition im Vordergrund. Dort, wo es um popul\u00e4re Musik geht, stellt sich zum anderen die Frage, ob und wie sich die Textverfahren von den bereits etablierten unterscheiden. Gegenstand der Untersuchung sind unter anderem Romane von Hans-Ulrich Treichel, Helmut Krausser, Tobias O. Mei\u00dfner und Rainald Goetz"
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"\u00dcbers. des Hauptsacht.: Narrated music in German contemporary fiction - studies to Treichel, Krausser, Mei\u00dfner and Goetz",
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<|eot_id|> |
3A782418570.jsonld | Document
### Text: {
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"(classificationName=ddc-dbn)590",
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],
"title": "Integrative statistical methods for decoding molecular responses to insect herbivory in Nicotiana attenuata",
"abstract": "This work focuses on the development of statistical methods to select features (genes and metabolites) exhibiting induced local and systemic defense responses to insect attack in Nicotiana attenuata along with the extraction of additional information regarding their timing of action. To characterize the dynamics of activation in time and space of herbivory-induced responses, I designed a framework by combining methods previously developed for feature selection and extraction to identify activated network motifs. These motifs are the set of features that are differentially perturbed in local and systemic tissues in response to herbivory. ...",
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<|eot_id|> |
3A782853390.jsonld | Document
### Text: {
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"CHO-K1 cells",
"Mitochondrienisolation",
"(classificationName=ddc-dbn)570",
"CHO-K1-Zellen",
"Zellaufschluss",
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"Zellkompartimentierung",
"Mitochondrien",
"kompartimentierter Stoffwechsel",
"microfluidics",
"cell compartmentalization",
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"title": "Neue Ans\u00e4tze zur systembiologischen Untersuchung der Mitochondrien und des Metabolismus in tierischen Zellkulturen",
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"Metabolomic analysis constitutes a crucial step for understanding cellular functions at a genomic level. In particular for systems biology studies, e.g. to describe the interplay of metabolic reactions and their dynamics, a reliable metabolomic analysis under physiological or in vivo conditions is required. While genomic, proteomic, and transcriptomic data can be obtained with high accuracy nowadays, the determination of metabolic profiles and fluxes still proves to be complicated. On the one hand, this is due to the fast turnover rates, the interaction between various metabolic pathways, and the chemical diversity of metabolites. On the other hand, the compartmentalization of metabolism in mammalian cells poses a huge challenge because of the dynamic range of metabolite concentration within the cytosol and the mitochondria. To overcome these limitations of metabolomic analysis, attempts have been made in this work to achieve a fast and efficient separation of the cytosolic and mitochondrial compartments by using new technological approaches in both macro and microscales. Due to its significant value, the well-known industrial cell line CHO-K1 was used as a model organism within this research project. To investigate the isolation of mitochondria in macroscale, different cell disruption methods were modified and tested. The efficiency and sensitivity of each were determined by the measure of mitochondrial yield and the integrity of isolated mitochondria. Here, the highest yields of intact mitochondria were obtained using ultrasound for cell disruption and subsequent differential centrifugation. In addition to the large-scale procedures, a microfluidic device for metabolic analysis, providing a complete sample preparation (including cell disruption) within seconds, was developed in project cooperation. In this work, a prototype of the Lab-on-a-Chip (LoaC) was successfully integrated into a bioreactor and operated for a period of 18 h. Continuous sampling was carried out by applying overpressure onto the bioreactor. Besides dynamic pulse experiments, this microchip-bioreactor system implemented an efficient separation of cells and extracellular media. Moreover, a selective cell lysis using digitonin and a subsequent separation of released cytosol from the remaining cellular and mitochondrial compartments was realised on-chip. Thus, this integrated microfluidic system provides high potential to overcome the limitations of analyses concerning compartmentalized metabolism. In the last part of this work, CHO-K1 cells were cultivated in a controlled small-scale bioreactor in order to perform systems biology studies. Therefore, detailed analyses of extracellular metabolites using LC-MS were performed under batch and continuous cultivation conditions. In addition, the mitochondrial structure and distribution of mitochondrial proteins were studied using confocal and high resolution STED microscopy. Furthermore, the relative level of enzymes involved in metabolic reactions was measured intracellularly by using the in-cell ELISA technology. To investigate the dependence of metabolic reactions on different cell cycle phases, the cultivation of synchronized cells was performed. For this purpose, cells from heterogeneous populations were enriched in the G1- and S-phase, respectively, using the centrifugal elutriation method. The synchrony during batch cultivation was determined flow cytometrically by analysing the DNA content and the cell size distribution. In addition, the cell count was observed continuously due to the effective integration of an at-line microscope. Metabolomic and microscopic studies of synchronized cells were performed during cultivation and the resultant data were compared to that obtained during cultivation of heterogeneous cell populations. The cell cycle dependency of metabolism was shown by the increased consumption rates of glucose and glutamine within the S-phase and the shifted increased lactate production during G1-phase, amongst others.",
"Metabolomische Analysen bilden einen entscheidenden Schritt zum Verst\u00e4ndnis zellul\u00e4rer Funktionen auf genomischer Ebene. Verl\u00e4ssliche metabolomische Analysen unter physiologischen oder in vivo Bedingungen werden insbesondere f\u00fcr systembiologische Untersuchungen zur Beschreibung der Interaktionen von Stoffwechselreaktionen und ihrer Dynamik ben\u00f6tigt. W\u00e4hrend genomische, proteomische und transkriptomische Daten heutzutage mit hoher Pr\u00e4zision generiert werden k\u00f6nnen, gestaltet sich die Bestimmung von Metabolitenprofilen nach wie vor schwierig. Dies liegt einerseits an den schnellen Umsatzraten, den Wechselwirkungen zwischen verschiedenen Stoffwechselwegen und der chemischen Diversit\u00e4t von Metaboliten. Auf der anderen Seite bildet die Kompartimentierung des Stoffwechsels tierischer Zellen eine gro\u00dfe Herausforderung, da hierdurch eine dynamische Spannbreite von Metabolitkonzentrationen innerhalb des Zytosols und der Mitochondrien vorliegt. Zur Bew\u00e4ltigung der Schwierigkeiten der Zellkompartimentierung wurde in der vorliegenden Arbeit der Versuch unternommen, die schnelle und effiziente Separation zytosolischer und mitochondrialer Kompartimente von S\u00e4ugetierzellen durch neue technologische Ans\u00e4tze sowohl im Makroma\u00dfstab als auch im Mikroma\u00dfstab, auf einem Lab-on-a-Chip (LoaC), zu erzielen. Wegen ihrer beachtlichen industriellen Bedeutung wurde innerhalb dieser Forschungsarbeit die Suspensionszelllinie CHO-K1 als Modell-organismus verwendet. F\u00fcr die Mitochondrienisolation im Makroma\u00dfstab wurden verschiedene Zellaufschlussverfahren modifiziert und getestet. Die Effizienz und Sensitivit\u00e4t einer jeden Methode wurden durch die Messung der Mitochondrienausbeute und der Integrit\u00e4t isolierter Mitochondrien bestimmt. Hierbei konnten die h\u00f6chsten Ausbeuten intakter Mitochondrien f\u00fcr einen Zellaufschluss mittels Ultraschall und anschlie\u00dfender differentieller Zentrifugation erzielt werden. Parallel zu den makroskopischen Methoden wurde als Kooperationsprojekt ein Mikrochipsystem entwickelt, das innerhalb weniger Sekunden eine vollst\u00e4ndige Probenverarbeitung (einschlie\u00dflich Zellaufschluss) f\u00fcr metabolische Analysen erm\u00f6glichen sollte. Der Prototyp des LoaC wurde innerhalb dieser Arbeit erfolgreich in einen Bioreaktor integriert und f\u00fcr eine Gesamtdauer von 18 h betrieben. Eine kontinuierliche Probenahme konnte hierbei mittels \u00dcberdruck realisiert werden. Neben dynamischen Pulsexperimenten wurde durch dieses Mikrochip-Bioreaktor-System eine effiziente Separation der Zellen vom extrazellul\u00e4ren Medium erzielt. Durch eine vorangestellte Zelllyse mittels Digitonin und die anschlie\u00dfende Abtrennung des freigesetzten Zytosols von den verbleibenden zellul\u00e4ren und mitochondrialen Kompartimenten, erwies das integrierte Mikrochipsystem gro\u00dfes Potential, um die Limitierungen zur Analyse des kompartimentierten Metabolismus zu \u00fcberwinden. Im letzten Teil der Arbeit wurden die CHO-K1 Zellen f\u00fcr systembiologische Untersuchungen in einem geregelten Kleinma\u00dfstab-bioreaktor kultiviert. Hierf\u00fcr wurden neben Batch-Verfahren ebenfalls kontinuierliche Kultivierungen von Mischpopulationen durchgef\u00fchrt und detaillierte extrazellul\u00e4re Metabolitanalysen mittels LC-MS vorgenommen. Dar\u00fcber hinaus wurden durch konfokale und hochaufl\u00f6sende STED-Mikroskopie die Mitochondrienstrukturen und die Verteilung mitochondrialer Proteine in Abh\u00e4ngigkeit von den Kultivierungsbedingungen analysiert. Zudem konnte der relative Gehalt stoffwechselrelavanter Enzyme intrazellul\u00e4r durch Einsatz der ELISA-Technologie bestimmt werden. Zur Untersuchung der Abh\u00e4ngigkeit meta-bolischer Reaktionen vom Zellzyklus wurden Kultivierungen synchronisierter Zellen erfolgreich durchgef\u00fchrt. Hierzu wurden die Zellen im Vorfeld aus heterogenen Populationen mittels Elutriationszentrifugation in der G1- bzw. der S-Phase angereichert. Die Synchronit\u00e4t \u00fcber den Zeitraum einer Batch-Kultivierung konnte mittels durchflusszytometrischer Analysen zur Bestimmung des DNA-Gehalts und des Zelldurchmessers sowie durch die erfolgreiche Applikation eines at-line Mikroskops zur kontinuierlichen Bestimmung der Zellzahl verfolgt werden. Metabolische und mikroskopische Untersuchungen synchronisierten Zellen wurden parallel dazu durchgef\u00fchrt und mit den Daten der Kultivierungen von Mischpopulation verglichen. Unter anderem durch deutlich erh\u00f6hte Verbrauchsraten der Hauptsubstrate Glukose und L-Glutamin in der S-Phase und eine versetzt eintretende erh\u00f6hte Bildung von Laktat w\u00e4hrend der G1-Phase, konnte eine Zellzyklusabh\u00e4ngigkeit des Metabolismus gezeigt werden."
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3A78286564X.jsonld | Document
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"title": "Information security management and employees' security awareness : an analysis of behavioral determinants",
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3A785246266.jsonld | Document
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3A785492739.jsonld | Document
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"title": "Towards self-assembled metamaterials",
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3A785499377.jsonld | Document
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"title": "Microglia differentiation and cell therapie",
"abstract": "Microglia Therapy: Diseases like Alzheimer or Multiple Sclerosis have been linked to a continuous deterioration of the resident microglia cell population. The brain, like other organs, also suffers from age related inflammation (\u201cinflamm-aging\u201d) and chronic activation of microglia. A cell therapy could aim to replace deteriorated microglia or to regulate the excessive activation of microglia in age. We wanted to differentiate microglia from adult stem cells (Paper 1 and 2) and to proof their function (phagocytosis, oxidative burst, migration). Then, we planned to transplant their progenitors and the differentiated microglia (Paper 3 and additional data). We also wanted to transplant mesenchymal stem cells (MSC) since MSC are known to regulate inflammation.",
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<|eot_id|> |
3A785774580.jsonld | Document
### Text: {
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"Diese Arbeit widmet sich der Entwicklung der Theorie der Fourier Hyperfunktionen mit Werten in einem nicht notwendigerweise metrisierbaren lokal konvexen Raum E und dem Aufsp\u00fcren von notwendigen und hinreichenden Bedingungen daf\u00fcr, dass eine vern\u00fcnftige Theorie E-wertiger Fourier Hyperfunktionen m\u00f6glich ist. Insbesondere wird gezeigt, dass, wenn E ein ultrabornologischer PLS-Raum ist, eine solche Theorie genau dann existiert, wenn E die sogenannte Eigenschaft (PA) besitzt. Desweiteren werden zahlreiche Beispiele solcher R\u00e4ume, die (PA) besitzen bzw. nicht besitzen, angegeben. Au\u00dferdem wird bewiesen, dass die vektorwertigen Fourier Hyperfunktionen als von \u00c4quivalenzklassen bestimmter E-wertiger Funktionale mit kompaktem Tr\u00e4ger dargestellt und als Randwerte von langsam wachsenden holomorphen Funktionen angesehen werden k\u00f6nnen. <dt.>"
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<|eot_id|> |
3A790301725.jsonld | Document
### Text: {
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"title": "Synthese und Modifizierung von Kathodenmaterialien f\u00fcr Lithiumionenbatterien",
"abstract": "Lithiumionenbatterien, Kathodenmaterial, Lithiumeisenphosphat, Organofunktionalisierung, Kohlenstoffbeschichtung. - Lithium-ion batteries, cathode material, lithium iron phosphate, organofunctionalization, carbon coating",
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<|eot_id|> |
3A794299377.jsonld | Document
### Text: {
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"\"Work in morphology is typically concerned with productive word formation and regular inflection, in any event with open class categories such as verbs, nouns, and adjectives, and their various forms. The Architecture of Determiners, by contrast, is devoted to a set of function words: the closed class of determiners. While it is traditionally assumed that function words are syntactically atomic, Thomas Leu shows that a comparative perspective on a series of determiners - each insistently vivisected into its minimal morphotactic segments - reveals an anatomy with properties analogous to clausal syntax, including a lexical, an inflectional, and left peripheral layer, as well as transformational relations among subconstituents. Leu argues that determiners are extended adjectival projections with a closed class minimal stem. Leu focuses on Swiss German and German, using other Germanic and non-Germanic languages as a comparative domain. His discussion of the internal structure of determiners includes demonstratives (ch.2), distributive quantifiers (ch.4), possessive and negative determiners (ch.5), and interrogative determiners such as 'was f\u00fcr' (ch.6). His main claim - that all of these involve extended adjectival projections - connects naturally to a discussion of adjectival / determiner inflection in German. Chapter 3 addresses the oft-debated strong versus weak agreement alternation in a novel way, proposing that the adjective moves within its own extended projection, in a way akin to verb movement to C in the clause. This accounts for the central facts of nominative and accusative inflection. Chapter 7, then, addresses dative and genitive morphology, setting them syntactically apart from adjectival / determiner inflection in a way that leads to a surprising account of most of the systematic (meta-) syncretism patterns in German adjectival inflection\"--"
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<|eot_id|> |
3A797412859.jsonld | Document
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"abstract": "This corpus pragmatic study addresses the symptomatic function of lexical and grammatical constructions in relation to the speaker's affiliation with groups that develop discourses through their shared social position. It uses a corpus of spoken and written communications on the bioethics debate to examine qualitative and quantitative correlations between spoken and written verbal patterns and roles, medium and context --",
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3A79792728X.jsonld | Document
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3A79819586X.jsonld | Document
### Text: {
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3A798285168.jsonld | Document
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<|eot_id|> |
3A798942630.jsonld | Document
### Text: {
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"title": "A decision support model for waste management in support of developing low carbon, eco region : case studies of densely populated kampung setllements in urban areas in Jakarta",
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"Due to the various types of waste disposal, treatment, utilization and technologies, decision support model for waste management is needed to assist planners and decision makers in finding most suitable way to manage municipal solid waste efficiently. Many planners and decision makers in the area of municipal solid waste have a lack of thorough understanding of the complex chains of waste management system. Therefore the impact for the environment quality and the public health can only be judged at the rudimentary level. However, most existing models are primarily focusing on cost or environmental analysis. Only few consider other crucial factors such as the demographic condition, the characteristics of urban form and urban infrastructure, land transformation aspects due to urban development. Consequently, such models often meet difficulties to cope with cultural requirement. Based on those reasons, a decision support model to set up alternatives of most appropriate technology for sustainable waste management towards a low carbon eco-city on a regional basis is developed in this PhD study. The Low Carbon- and Eco-Region, in particular the contribution of waste management sector, is a vision of living in low rate of carbon generation, using fewer natural resources, and encouraging energy recovery and/or waste reduction at source by improving the used material quality (up-cycling). This decision support model is constructed mainly based on the cultural requirement and local context of a region and synergize the geographic, environmental, social capital and economics aspects in order to fulfill the needs of the respective region and its society. The method employed in this model is not solely a new developed model, but also an advanced model in material flow analysis (STAN), and life cycle assessment on solid waste system (EASEWASTE) and Geographic Information System (GIS). At the same time the model also assists the stakeholders in improving the environmental quality and the public health by promoting waste separation at source and reducing the greenhouse gas emission potential from waste sector.",
"Aufgrund der vielfaltigen Techniken und Methoden der Abfall- Entsorgung, -Behandlung und -Wiederverwendung ist ein Entscheidungshilfe-Modell ben\u00f6tigt, um die Entwerfer und Entscheidungstr\u00e4ger bei der Suche nach der effektivsten Managementmethode der Kommunalabf\u00e4lle zu unterst\u00fctzen. Viele Planer und ET im Bereich der Kommunalabfall haben mangels vollst\u00e4ndiger Kenntnisse \u00fcber die komplizierten Abl\u00e4ufe des Kommunalabfallmanagementsystems, deswegen kann der Einfluss auf die Qualit\u00e4t der Umwelt und die allgemeine Gesundheit nur auf rudiment\u00e4ren Ebene gemessen werden. Allerdings konzentrieren sich die meisten existierten Modelle vor allem auf die Kosten oder die Umweltanalyse, nur wenige ber\u00fccksichtigen andere entscheidende Faktoren, wie die demografischen Bedingungen, die Eigenschaften der Stadtform und st\u00e4dtischen Infrastruktur, Land-Transformationsaspekte durch Stadtentwicklung. Deshalb haben solche Modelle oft Schwierigkeiten mit den kulturellen Bed\u00fcrfnissen zurechtzukommen. Auf dieser Grundlage ist, ein Modell zur Entscheidungshilfe f\u00fcr das Einrichten von Alternativen f\u00fcr die meist geeigneten Technologien f\u00fcr nachhaltiges Kommunalabfallmanagement nach einem niedrige-Kohlstoff- und \u00d6ko-stadt auf regionale Ebene ist bei dieser Promotion entwickelt worden. Die niedrig Kohlenstoff und \u00d6koregion, insbesondere die Beteiligung des Kommunalabfallmanagementsektors ist eine Vision um in einer niedrigen Kohlenstoff-Erzeugungsrate zu leben, weniger nat\u00fcrliche Ressourcen zu benutzen, und Zur\u00fcckgewinnung von Energie zu f\u00f6rdern mit/ohne an der Quelle Abfallminimierung durch die Verbesserung der Qualit\u00e4t von angewendeten Materialien (up-cycling). Dieses Entscheidungshilfe-Modell ist haupts\u00e4chlich aufgebaut auf der Grundlage der kulturellen Bed\u00fcrfnisse und dem lokalen Zusammenhang einer Region, es synergiert alle geografische, \u00f6kologische, soziale und wirtschaftliche Aspekte, um die Bed\u00fcrfnisse der entsprechenden Region und derer Gesellschaft. Die in diesem Modell verwendete Methode ist nicht nur ein neu entwickeltes Modell, sondern auch ein fortschrittliches Modell, das mit der Materialflussanalyse (STAN), der \u00d6kobilanz von Kommunalabfallsystemen (EASEWASTE) und dem Geografischen Informationssystem (GIS) entwickelt worden ist. Gleichzeitig unterst\u00fctzt das Modell die Interessenvertreterin bei der Verbesserung der Qualit\u00e4t der Umwelt, und die allgemeine Gesundheit, durch die F\u00f6rderung der an der Quelle gesteuerte Abfalltrennung, und Reduzierung des Potenzials an Treibhausgasemissionen aus dem Abfallsektor."
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"alternative": "Ein Entscheidungs-Hilfe-Modell f\u00fcr Abfallmanagement zur F\u00f6rderung der Entwicklung von kohlenstoffarmen \u00d6koregionen : Fallstudien \u00fcber dicht bev\u00f6lkerte Kampung-Siedlungen in st\u00e4dtischen Gebieten in Jakarta",
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3A800071492.jsonld | Document
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"title": "Erziehungskonzepte der Krippeneinrichtungen der DDR : eine vergleichende Analyse unter besonderer Ber\u00fccksichtigung des Verh\u00e4ltnisses von Selbst\u00e4ndigkeit und p\u00e4dagogischer Anleitung",
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"The thesis deals with nursery concepts which were developed in the GDR in the years 1956, 1957, 1968 and 1985. The study mainly focuses on the question of the relationship between autonomy and pedagogical guidance. Further issues are the possible usability of innovative contents in the final program of 1985 and the role of the social hygienist Eva Schmidt-Kolmer. The text analyses follow an introductory theoretical part on early childhood education and the education and nursery system in the GDR. A variety of categories which are essential for the early childhood sector, for instance the child image or the role of the educators, form the basis of the analysis. As a result, it is clear that the reforms of the program of 1985 could not prevail without restrictions. Due to rigid development and educational goals the allowance of self-education processes remained limited. However, the analysis of a different concept (2004), which is based on the program of 1985, also shows that various contents are indeed transferable and can be utilized for the training of early childhood care. <engl.>",
"Die Arbeit untersucht die Krippenkonzepte der DDR aus den Jahren 1956, 1957, 1968 und 1985. Den Untersuchungsschwerpunkt bildet die Frage nach dem Verh\u00e4ltnis von Selbstst\u00e4ndigkeit und p\u00e4dagogischer Anleitung. Weitere Fragestellungen sind die nach m\u00f6glichen innovativen Inhalten im letzten DDR-Programm von 1985 und die nach der Rolle der Sozialhygienikerin Eva Schmidt-Kolmer. Die Textanalysen erfolgen im Anschluss an einen einf\u00fchrenden theoretischen Teil zu fr\u00fchkindlicher P\u00e4dagogik und dem Bildungs- und Krippenwesen der DDR. Als Analyseinstrument fungieren verschiedene f\u00fcr den fr\u00fchkindlichen Bereich grundlegende Kategorien (z. B. das Kindbild und die Erzieherinnenrolle). Im Ergebnis wird deutlich, dass sich Reformen im 1985er-Programm nur begrenzt durchgesetzt haben. Das Zulassen von Selbstbildungsprozessen bleibt auch hier aufgrund der starren Entwicklungs- und Erziehungsziele beschr\u00e4nkt. Die Analyse eines weiteren Konzepts (2004), das an das Erziehungsprogramm von 1985 anlehnt, zeigt aber auch, dass verschiedene Inhalte transferierbar sind und f\u00fcr die Qualifizierung fr\u00fchkindlicher Betreuung nutzbar gemacht werden k\u00f6nnen. <dt.>"
],
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"Educational concepts in nurseries in the GDR: a comparative analysis with particular reference to the relationship between autonomy and pedagogical guidance",
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<|eot_id|> |
3A802898262.jsonld | Document
### Text: {
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"title": "Molekularbiologische Analyse des chemischen Abwehrsystems bei Blattk\u00e4ferlarven (Coleoptera: Chrysomelina) : in vivo Validierung von Enzymen und Transportproteinen an essentiellen Schnittstellen des Defensiv-Metabolismus mittels RNA interference",
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<|eot_id|> |
3A805298363.jsonld | Document
### Text: {
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<|eot_id|> |
3A80556800X.jsonld | Document
### Text: {
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"The study can be divided into three sections. In the first section, wood was treated with different commercially available silica sols of varying pH and surface modification. While alkaline silica sols could not be impregnated into the wood due to lowering of pH and precipitation, neutral and acidic silica sols showed good penetration. One of the tested silica sols with an acidic pH value and cationic surface modified with aluminum-oxychloride reduced water uptake and fungal decay due to incubation with the brown rot fungus Coniophora puteana (pine sapwood) and the white rot fungus Trametes...",
"Diese Arbeit besteht aus drei Teilen. Im ersten Teil wurde Holz mit verschiedenen, kommerziell erh\u00e4ltlichen Kieselsolen behandelt, die unterschiedliche pH-Werte und Oberfl\u00e4chenmodifikationen aufwiesen. Basische Kieselsole vermochten nicht in das Holz einzudringen, da ihr pH-Wert w\u00e4hrend des Eindringens absinkt und es zur Ausf\u00e4llung des Kieselsols im Holz kommt. Neutrale und saure Kieselsole hingegen konnten problemlos in das Holz eingebracht werden. Eines der sauren Kieselsole, welches mittels Aluminumoxychlorid kationisch modifiziert war, reduzierte die Wasseraufnahme und den pilzlichen Ab..."
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<|eot_id|> |
3A812604172.jsonld | Document
### Text: {
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"(classificationName=linseach:mapping)bio",
"(classificationName=linseach:mapping)cet",
"(classificationName=bk, id=106421492)42.51 - Mycophyta, Lichenes"
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"title": "Biotechnologische Erzeugung nat\u00fcrlicher Aromastoffe aus Submerskulturen von Asco- und Basidiomyceten",
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<|eot_id|> |
3A813015448.jsonld | Document
### Text: {
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3A81416238X.jsonld | Document
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3A815369484.jsonld | Document
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3A815620535.jsonld | Document
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3A818828099.jsonld | Document
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"abstract": "Single-electron pump, dynamic quantum dot, counting statistics, charge detection, quantum ampere. - Einzel-Elektronen-Pumpe, dynamischer Quantenpunkt, Z\u00e4hlstatisitik, Ladungsdetektion, Quanten-Ampere",
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<|eot_id|> |
3A820450189.jsonld | Document
### Text: {
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"title": "All inkjet printed piezoelectric polymer actuators for microfluidic lab-on-a-chip systems",
"abstract": "Printing technologies for the fabrication of electronic components have emerged in recent years and have attracted interest due to their capabilities of cost-effective material deposition and their suitability for large-area coatings. In this thesis, the benefits of inkjet printing technologies are used to manufacture piezoelectric actuators that are suitable for integration in polymer-based, disposable microfluidic lab-on-a-chip (LOC) systems. Based on analytical models of actuator behavior, piezoelectric actuators with poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) as the active material are inkjet printed and characterized in detail for the first time here. The thermal treatment applied to the P(VDF-TrFE) films exhibits a significant influence on device performance and morphology. Annealing at temperatures between 110 and 140 \u00b0C yields distinct piezoelectric behavior. These findings are employed to demonstrate the function of a membrane pump with an inkjet printed actuator with pump rates up to 130 \u00b5L/min, which is suitable for applications in LOC systems. Compared to the state-of-the-art, the manufacturing approach introduced here as well as the established knowledge about the behavior of inkjet printed P(VDF-TrFE) actuators are novel. The low processing temperatures and the use of digital printing technologies lead to cost-effective processing compared to conventional, lithography- and vacuum-based manufacturing approaches. Different from most current micropumps, an additional assembly step is not required, which would be necessary when an actuator is manufactured separately and then attached to the pump membrane. Furthermore, the manufacturing approach and design introduced here are compatible with processes and materials that are used in LOC systems. They allow a cost-effective integration of further functionalities, leading to a higher degree of integration and thus smarter systems.",
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<|eot_id|> |
3A82160516X.jsonld | Document
### Text: {
"@graph": [
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"sameAs": "Technische Universit\u00e4t Hamburg-Harburg, Institut f\u00fcr Umwelttechnik und Energiewirtschaft"
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"subject": [
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"Biogas",
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"title": "Outdoor cultivation of Chlorella vulgaris : assessment of yield influencing parameters and application as biogas substrate",
"abstract": [
"Microalgae offer a great potential as feedstock for a variety of high-value products and biofuels. The production of microalgae biomass requires, however, high efforts and consequentially large-scale outdoor production facilities are still a rarity today. The aim of this investigation is therefore to set-up and to operate an outdoor, high-density microalgae culture to monitor, analyse, and interpret the complex processes that unfold in the system. The research addresses important aspects including productivity and composition of microalgae cultivated outdoors and the effect of flue gas on microalgae growth. Moreover, the potential of biogas production from microalgae as a promising processing option is evaluated.$cen$dAbstract",
"Mikroalgen besitzen gro\u00dfes Potential als Rohstoff f\u00fcr hochwertige Produkte und Biokraftstoffe. Eine Freilandkultivierung im gro\u00dfen Ma\u00dfstab ist jedoch sehr aufw\u00e4ndig und wird daher selten umgesetzt. Das Ziel dieser Untersuchung ist es, die komplexen biologischen Prozesse in einer Pilotanlage zur Kultivierung von Mikroalgen unter Freilandbedingungen zu beobachten, zu analysieren und zu interpretieren. Insbesondere der Effekt hochvariabler Umwelteinfl\u00fcsse, wie Licht und Temperatur, auf Produktivit\u00e4t und biochemische Zusammensetzung stehen hier im Fokus. Des Weiteren werden der Einfluss von Abgas auf das Wachstum der Algen und die Interaktion zwischen Bakterien und Mikroalgen in den Reaktoren untersucht. Im Anschluss an die Kultivierung wird die Produktion von Biogas aus Mikroalgenbiomasse als m\u00f6glicher Prozessweg evaluiert.$cde_DE$dAbstract"
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<|eot_id|> |
3A821871145.jsonld | Document
### Text: {
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{
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},
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],
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"subject": [
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"(classificationName=bk, id=18157134X)74.08 - Wirtschaftsgeographie",
"Kola (Halbinsel)",
"Russland",
"(classificationName=linseach:mapping)geo",
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"Verkehrsgeographie",
"Murmansk (Oblast)",
"(classificationName=ddc-dbn)320",
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"Regionalentwicklung",
"(classificationName=rvk)RQ 15909",
"(classificationName=ddc-dbn)330",
"(classificationName=ddc)330.94713"
],
"title": "M\u00f6glichkeiten und Grenzen moderner Regionalentwicklung in den Regionen des russischen Nordens am Beispiel der Oblast' Murmansk",
"abstract": [
"Located on the Kola Peninsula, Murmansk region was the first territorial unit with a polar climate that is equipped with significant mining structures worldwide, to satisfy the demand of young Soviet Union for raw materials. Due to the importance of the found items here (apatite, nonferrous metals, iron, mica, rare earths) numerous cities and settlements have been established in this climatically very difficult region. From 1920 to 1990 the population grew by 50 times to approx. 1.2 million. Beyond its importance as a supplier of raw materials the region became a traffic junction for soviet foreign trade and supply of Siberian mining sites and also a base for strong military forces, especially the Northern fleet (including nuclear submarines with ICBMs) and structures of Strategic air defense. Although economic profile and importance to the mother country could be obtained after collapse of the Soviet Union, there are serious socio-economic problems, whose greatest consequence is a compared to Russian average extreme population loss (1990 - 2014 approx. 33%). With the objective of evaluating future opportunities and risks, the present research describes the current socio-economical structures of the Murmansk region and their integration into administrative, fiscal and economic hierarchies of Russia. The structures, processes, and based on these conclusions are exemplary for most of the other regions of the Russian \"Far North\".",
"Murmansk, Russland, Regionale Geographie, Wirtschaftsgeographie, Oblast Murmansk, Halbinsel Kola, Verkehrsgeographie, Russland / Vooru\u017ee\u034f\u0308nnye Siss"
],
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<|eot_id|> |
3A825930804.jsonld | Document
### Text: {
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"title": "Zeolite and metal-organic framework membranes for pervaporation and gas separation",
"abstract": "Zeolite membrane, MOF membrane, gas separation, pervaporation, ion-exchange, pre- and post-modification method. - Zeolithe-Membranen, MOF-Membranen, Gastrennung, Ionenaustausch, Pre- und Post-Funktionalisierung",
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<|eot_id|> |
3A827012632.jsonld | Document
### Text: {
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"title": "Between the Urban and the Rural : Back to the city",
"abstract": "Abstract This doctoral thesis defines the relationship between the urban and rural in the 21st century, and focuses on food as a key component. The fact that food is, for the most part, produced in the countryside and then transported to the city has a significant influence on this very unbalanced relationship today. The main goal was to show that it is necessary to bring agriculture, urban gardening, the breeding of domestic farm animals, and beekeeping back to the city, which would have a positive affect on both the city and the countryside. All of this is already taking place at the local level, within the neighbourhoods of our cities and through the work of self-organised activities and initiatives, which have been taken up by city residents themselves. One example of this is the community garden, a new model of gardening which offers fertile ground for growing vegetables and to test various forms of co-existence, different ways of designing spaces, the creation of alternative values, and a positive vision for the future of city residents. In 2010, I co-created the community urban garden Beyond a Construction Site, which is the central part of this artistic research. Throughout the entire four-year process of creating this community garden, theory and artistic practice were intertwined, and informed one another. This community garden is an example of a self-organised and self-managed community space located in a residential neighbourhood in the centre of the city of Ljubljana, and as such is a typical example of urbanism from the bottom up. I placed the creation and development of our community garden in a dialogue with the formal way of arranging urban gardening in Ljubljana, a top-down approach, which the city has been carrying out intensively since 2007. I compared the solutions being proposed by the city of Ljubljana for organising urban gardening with the way it is organised in other European cities, the UK, and the USA. I also researched the recent rapid growth of self-organised initiatives which are focused on the local production of food and seek to find more economic and ecologically friendly models to visibly influence the future of cities and the countryside. Here, community gardens play an important role, as in addition to the production of food they are also spaces for the criticism of existing urban policies, a self-organised revitalisation of neglected spaces, and places of resilience, because they differ from that which real estate agencies, large financial companies, and city authorities desire them to be. The community garden Beyond a Construction Site has become living proof that, through a group action, the residents of a neighbourhood can influence existing city policies and the future of both their own neighbourhood and that of the entire city. The initiators of this garden are artists and architects, and we began this community garden in the context of an art festival, which also shows that art can influence the processes of everyday life and help to create much needed spaces within cities to serve various purposes. Our community garden has also shown itself to be an important platform for the exchange of knowledge on organic gardening, ecology in everyday life, and critical architecture, as well as serving to connect related initiatives. Together with these other initiatives we are stronger, and are influencing structural changes within city politics, thereby also co-creating the future of Ljubljana. This community garden is helping us to redefine our relationship with the city and re-awaken the desires and actions of residents connected with realising their fundamental right, the right to the city. My other artworks, which I am presenting in the context of this doctoral thesis, show an optimistic vision for the future of cities. The video animations Back to the City (2011) and The Right Balance (2013), as well as the accompanying collages, visualise a city of the future where urban and rural practices live together side-by-side. This vision is being realised by city residents themselves, with their active participation in the creation of community gardens, growing their own vegetables, urban beekeeping, and by having egg-laying hens in their gardens. My desire was also to present the theoretical concept and scientific research to a non-academic public, and to people without specialised training. Using the method of storytelling I included knowledge from the research into the video animations and collages. In this way my artistic work, with an intentional playfulness, challenges today\u2019s faith in science and theoretical concepts, as well as directing attention to working with common sense, with one\u2019s own hands, and with the earth. This can contribute to a change in the still dominant anthropocentric view of nature, which is an urgently needed change for our future. Keywords: rural, urban agriculture, community gardens, urban beekeeping, the bottom-up approach to urban planning, alternative spaces",
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<|eot_id|> |
3A827086695.jsonld | Document
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"title": "Unveiling the epoch of reionization by simulations and high-redshift galaxies",
"abstract": "The Epoch of Reionization marks after recombination the second major change in the ionization state of the universe, going from a neutral to an ionized state. It starts with the appearance of the first stars and galaxies; a fraction of high-energy photons emitted from galaxies permeate into the intergalactic medium (IGM) and gradually ionize the hydrogen, until the IGM is completely ionized at z~6 (Fan et al., 2006). While the progress of reionization is driven by galaxy evolution, it changes the ionization and thermal state of the IGM substantially and affects subsequent structure and galaxy formation by various feedback mechanisms. Understanding this interaction between reionization and galaxy formation is further impeded by a lack of understanding of the high-redshift galactic properties such as the dust distribution and the escape fraction of ionizing photons. Lyman Alpha Emitters (LAEs) represent a sample of high-redshift galaxies that are sensitive to all these galactic properties and the effects of reionization. In this the\u2026",
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<|eot_id|> |
3A82734080X.jsonld | Document
### Text: {
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"title": "Tailorable system software",
"abstract": "...Over the last four years, my research has focused on methods and techniques to improve the design, implementation, and maintenance of static variability in highly tailorable system software. My central contributions in this respect are: (a) The CiAO approach, which employs language techniques to achieve excellent up-tailorability of embedded system software (towards the requirements of a specific application). (b) The Sloth approach, which employs generative techniques to achieve down-tailorability of embedded system software (towards better exploitation of modern commodity hardware). (c) The VAMOS approach, which employs cross-language analysis techniques and holistic variability modeling to improve on the long-term maintainability of multi-paradigmatic variability implementations in existing large-scale system software, such as Linux...",
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3A827936230.jsonld | Document
### Text: {
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<|eot_id|> |
3A828177554.jsonld | Document
### Text: {
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"title": "Die Kleruchien und Apoikien Athens im 6. und 5. Jahrhundert v. Chr. : Rechtsformen und politische Funktionen der athenischen Gr\u00fcndungen",
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"\"The Athenian Cleruchies and Apoikias constitute one pivotal instrument for the expansion and the consolidation of political power enabling Athens to evolve as the hegemonic polis in the Aegean Sea. This study presents a comprehensive discussion of all Athenian settlements in the sixth and fifth centuries B.C. with a focus on the formal analysis of the settlement types as well as the evaluation of political functions of the respective colonies\"--",
"Einleitung -- 'Kleruchie' und 'Apoikie' : Rechtssystematische und terminologische Grundlagen -- Die Apoikien Athens im 6. Jh. -- Diskussion der athenischen Gr\u00fcndungen des 5. Jh. in chronologischer Reihenfolge -- Systematisierung im Kontext athenischer Machtpolitik -- Ergebnisse"
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<|eot_id|> |
3A828645450.jsonld | Document
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"(firstid)GBV:828645450"
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"title": "Die wei\u00dfrussisch-russische gemischte Rede als Subvariet\u00e4t im Vergleich zu russischen nicht-hochsprachlichen Variet\u00e4ten und Wei\u00dfrussisch : Ph\u00e4nomene der Flexionsmorphologie",
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"In the following dissertation a comparison is drawn between inflectional morphological phenomena of two mainly spoken subvarieties, i.e. of the mixed Belarusian-Russian speech (Trasjanka) and Russian substandard Prostorechie. The analysis reveals that in the Trasjanka there are only few similarities to simple, regular structures of the Russian Prostorechie. These parallels are given only, if they are maintained by Belarusian. The Belarusian standard shares many similarities with the Russian Prostorechie. Nevertheless, not all of these regular forms can be found in the Trasjanka. This implies even in the situations when Russian demonstrates irregular forms, its model is preferred as the model of the social dominant \u201cprestige\u201d-language. It can be concluded that, while in general regular structures prevail in Prostorechie, in the Trasjanka a complex combination of sociolinguistic and \u201cinternal\u201d language factors is responsible for the distribution of forms. <engl.>",
"In der vorliegenden Arbeit werden die flexionsmorphologischen Ph\u00e4nomene zweier vorwiegend m\u00fcndlicher Subvariet\u00e4ten, und zwar der wei\u00dfrussisch-russischen gemischten Rede (WRGR) (\u201eTrasjanka\u201c) und des russischen \u201eProstoretschie\u201c (entsprechend einer niederen Umgangssprache) verglichen. Die Analyse zeigt, dass sich in der WRGR nur wenige Parallelen zu den einfacheren, regelm\u00e4\u00dfigen Strukturen des russischen Prostoretschie finden. Diese liegen nur dann vor, wenn sie vom Wei\u00dfrussischen unterst\u00fctzt werden. Das Wei\u00dfrussische zeigt viele morphologische Gemeinsamkeiten mit dem Prostoretschie. Jedoch k\u00f6nnen bei weitem nicht alle diese regelm\u00e4\u00dfigen Formen in der WRGR realisiert werden. D.h. auch in den Situationen, wo das Russische eher unregelm\u00e4\u00dfige Formen zeigt, wird sein Muster als das der sozial dominierenden \u201ePrestige\u201c-Sprache bevorzugt. Es l\u00e4sst sich feststellen, dass im Unterschied zum Prostoretschie, wo sich im Allgemeinen die regelm\u00e4\u00dfigen Strukturen durchsetzen, in der WRGR ein komplexes Zusammenspiel soziolinguistischer und innersprachlicher Faktoren f\u00fcr die Formenverteilung verantwortlich ist. <dt.>"
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<|eot_id|> |
3A829139001.jsonld | Document
### Text: {
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"(classificationName=bk, id=106405403)18.00 - Einzelne Sprachen und Literaturen allgemein",
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"title": "Memory limitations in sentence comprehension : a structural-based complexity metric of processing difficulty",
"abstract": "This dissertation addresses the question of how linguistic structures can be represented in working memory. We propose a memory-based computational model that derives offline and online complexity profiles in terms of a top-down parser for minimalist grammars (Stabler, 2011). The complexity metric reflects the amount of time an item is stored in memory. The presented architecture links grammatical representations stored in memory directly to the cognitive behavior by deriving predictions about sentence processing difficulty. Results from five different sentence comprehension experiments were used to evaluate the model's assumptions about memory limitations. The predictions of the complexity metric were compared to the locality (integration and storage) cost metric of Dependency Locality Theory (Gibson, 2000). Both metrics make comparable offline and online predictions for four of the five phenomena. The key difference between the two metrics is that the proposed complexity metric accounts for the structural complexity of intervening material. In contrast, DLT's integration cost metric considers the number of discourse referents, not the syntactic structural complexity. We conclude that the syntactic analysis plays a significant role in memory requirements of parsing. An incremental top-down parser based on a grammar formalism easily computes offline and online complexity profiles, which can be used to derive predictions about sentence processing difficulty.",
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<|eot_id|> |
3A829159045.jsonld | Document
### Text: {
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"title": "Asymptotische Analyse zuf\u00e4lliger diskreter Strukturen mit Methoden der diskreten Potentialtheorie",
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<|eot_id|> |
3A831916575.jsonld | Document
### Text: {
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"title": "Metalloxide zur thermochemischen Hochtemperaturw\u00e4rmespeicherung",
"abstract": "Thermochemische Energiespeicherung, Metalloxid, Gas/Feststoff-Reaktion. - Thermochemical energy storage, metal oxide, gas/solid-reaction",
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<|eot_id|> |
3A832557773.jsonld | Document
### Text: {
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"title": "Uncertainties in climate data analysis : perspectives on working with measurement errors and other unknowns",
"abstract": "Scientific inquiry requires that we formulate not only what we know, but also what we do not know and by how much. In climate data analysis, this involves an accurate specification of measured quantities and a consequent analysis that consciously propagates the measurement errors at each step. The dissertation presents a thorough analytical method to quantify errors of measurement inherent in paleoclimate data. An additional focus are the uncertainties in assessing the coupling between different factors that influence the global mean temperature (GMT). Paleoclimate studies critically rely on `proxy variables' that record climatic signals in natural archives. However, such proxy records inherently involve uncertainties in determining the age of the signal. We present a generic Bayesian approach to analytically determine the proxy record along with its associated uncertainty, resulting in a time-ordered sequence of correlated probability distributions rather than a precise time series. We further develop a recurrence based method to detect dynamical events from the proxy probability distributions. The methods are validated with synthetic examples and demonstrated with real-world proxy records. The proxy estimation step reveals the interrelations between proxy variability and uncertainty. The recurrence analysis of the East Asian Summer Monsoon during the last 9000 years confirms the well-known `dry' events at 8200 and 4400 BP, plus an additional significantly dry event at 6900 BP. We also analyze the network of dependencies surrounding GMT. We find an intricate, directed network with multiple links between the different factors at multiple time delays. We further uncover a significant feedback from the GMT to the El Ni\u00f1o Southern Oscillation at quasi-biennial timescales. The analysis highlights the need of a more nuanced formulation of influences between different climatic factors, as well as the limitations in trying to estimate such dependencies",
"alternative": "Unsicherheiten in der Analyse von Klimadaten",
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<|eot_id|> |
3A832934623.jsonld | Document
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"title": "From finite to infinite : cluster algebras as colimits, and mutating torsion pairs in discrete cluster categrories",
"abstract": "Cluster algebras of infinite rand, cluster categories, mutation of torsion pairs in triangulated categories. - Cluster-Algebren von unendlichem Rang, Cluster-Kategorien, Mutation von Torsionspaaren in triangulierten Kategorien",
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<|eot_id|> |
3A833064894.jsonld | Document
### Text: {
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"title": "Wiring the world : the social and cultural creation of global telegraph networks",
"abstract": "Acknowledgements -- Introduction: actors of globalization and the wiring of the world -- Atlantic beginnings : the class of 1866 and the formation of \"telegraphic\" networks -- Come to wire the world : world economy and the battle for Atlantic cable supremacy -- The imagined globe : of the electric union, universal peace and the \"great civilizer\" -- Weltcommunication : economic intelligence, global news and \"social messaging\" -- The world's telegraphic knowledge and the professionalization of the telegraph engineer -- The politics of the world's electric nerves : strategic nationalism, cable diplomacy, and imperial control -- Conclusion: the class of 1866 and globalization -- Appendix: the actors' biographies -- Bibliography",
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<|eot_id|> |
3A833239732.jsonld | Document
### Text: {
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"Die Arbeit untersucht, welche Auswirkungen der demografische Wandel auf die Haushalte kreisangeh\u00f6riger Gemeinden in Sachsen-Anhalt hat. Bev\u00f6lkerungsverluste f\u00fchren zu steigenden Pro-Kopf-Ausgaben in nahezu allen Bereichen, was die Remanenzkostenproblematik \u00f6ffentlicher Leistungserbringung verdeutlicht. Kommunen haben zudem kaum finanzielle Gestaltungsspielr\u00e4ume, denn knapp 90 % der Ausgaben sind durch Landes- und Bundesregelungen vorgegeben. Zudem zeigt sich, dass b\u00fcrgerschaftliches Engagement kein homogenes Gut ist, sondern sowohl bereichsspezifisch als auch getrennt nach Engagementformen untersucht werden sollte. Die Interaktionen zwischen \u00f6ffentlichen Ausgaben und b\u00fcrgerschaftlichem Engagement sind vielschichtig und lassen keine generelle Schlussfolgerung zu, wie sich b\u00fcrgerschaftliches Engagement ver\u00e4ndert, wenn Kommunen oder L\u00e4nder Ausgaben k\u00fcrzen. Im Kultur- sowie im Sozialbereich deutet sich an, dass B\u00fcrger ihr Engagement ausweiten, wenn \u00f6ffentliche Mittel in diesen Bereichen zur\u00fcckgehen.",
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<|eot_id|> |
3A834567830.jsonld | Document
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"title": "Measuring the Burden of Disease and Returns to Education in Rural West Africa : The Collection and Analysis of Mortality, Morbidity, and Socio-Economic Data in the Nouna Health District in Burkina Faso",
"abstract": "The success of health economics and its guidance for health policy heavily rests on the availability of reliable empirical evidence on the demographic, economic, and epidemiological environment, on behavioral relationships, and on the impact of policy interventions. For Sub-Saharan Africa, especially the epidemiological situation is unclear, since comprehensive systems of mortality and health statistics are often absent. -- The economic analysis of health naturally places a special focus on the interrelation between health and economic well-being: the overall disease burden decreases when a country grows richer, and the share of communicable diseases decreases in the process of economic development, whereas the share of non-communicable diseases increases. In those parts of Sub-Saharan Africa that are mainly dominated by traditional subsistence farming, however, it is difficult to examine questions of income and health for simple fundamental reasons. A vital prerequisite for an empirical investigation is the thorough and accurate measurement of income. Yet, both the measurement of the burden of disease and the measurement of income are research tasks that are far from being fulfilled for Sub-Saharan Africa. A further issue that is related with economic well-being and health is education. For poor rural regions predominated by traditional subsistence farming it is far from clear whether investments in human capital are worthwhile. -- The present study addesses this research gap by producing empirical evidence on the measurement of the burden of disease, the structure of income, and returns to education in rural West Africa. Concretely it deals with the collection and analysis of mortality, morbidity, and socio-economic data in the Nouna Health District in the North-West of Burkina Faso. The study was accepted as a doctoral thesis at the University of Heidelberg. Earlier versions of some of its chapters have been published as working papers or in international journals",
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<|eot_id|> |
3A83477416X.jsonld | Document
### Text: {
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"Berufliche Standards sind wesentliche Elemente eines Berufsbildungssystems. Die Standards definieren den Beruf, beschreiben die Qualifikationsanforderungen des Arbeitsmarktes und legen die zu erzielenden Ergebnisse von Bildungs- und Trainingsma\u00dfnahmen fest. In dieser Arbeit wird ein Qualit\u00e4tsverfahren theoriegeleitet entwickelt, um die im beruflichen Standard definierten Qualifikationsanforderungen mit dem aktuellen Qualifikationsbedarf des Arbeitsmarkts qualitativ und quantitativ zu \u00fcberpr\u00fcfen. Das Qualit\u00e4tsverfahren wurde an 8 verschiedenen Berufen iterativ entwickelt und bildet eine Erweiterung an bestehende Entwicklungsverfahren f\u00fcr berufliche Standards.$cde$dAbstract"
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<|eot_id|> |
3A834791048.jsonld | Document
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"title": "Essays on real estate and financial crisis : from the US housing market downturn to the global financial crisis",
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<|eot_id|> |
3A835050793.jsonld | Document
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"abstract": "Most of the baryonic matter in the Universe resides in a diffuse gaseous phase in-between galaxies consisting mostly of hydrogen and helium. This intergalactic medium (IGM) is distributed in large-scale filaments as part of the overall cosmic web. The luminous extragalactic objects that we can observe today, such as galaxies and quasars, are surrounded by the IGM in the most dense regions within the cosmic web. The radiation of these objects contributes to the so-called ultraviolet background (UVB) which keeps the IGM highly ionized ever since the epoch of reionization. Measuring the amount of absorption due to intergalactic neutral hydrogen (HI) against extragalactic background sources is a very useful tool to constrain the energy input of ionizing sources into the IGM. Observations suggest that the HI Lyman-alpha effective optical depth, \u03c4_eff, decreases with decreasing redshift, which is primarily due to the expansion of the Universe. However, some studies find a smaller value of the effective optical depth than expected at the sp\u2026",
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<|eot_id|> |
3A836076753.jsonld | Document
### Text: {
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<|eot_id|> |
3A836133811.jsonld | Document
### Text: {
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"title": "Design and synthesis of dithiolene based biomimetic compounds for metal ion sensors and oxo-transfer catalytic applications",
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"Because heavy metal ions prefer to bind sulfur, inspired by molybdopterin the main goal of this work was combining dithiolene binding moieties with optically active substituents with the aim to detect/capture metal ions, which could preferably bind to the dithiolene moiety of for instance MPT. Therefore a number of dithiolene based molecules mimicking the natural immediate coordination sphere composition of Mo and W dependent oxidoreductase enzymes were synthesized and characterized by NMR, MS, IR, X-ray crystallography, UV-Vis, EPR and electrochemical methods. In order to work at the lowest possible base concentration due to potentially base sensitive substituents and reaction partners, the procedure for the de-protection of the ligand precursors and the in situ complexation reaction was first optimized in course of the work and interim we explored the surprising fact that the ring opening reaction of the 1,3- dithiol-2-one system is fully reversible and can be controlled simply by adjusting the pH-value of the solution. Then, the coordination behavior of the de-protected ligands towards different metal ions, including biologically relevant ions like Cu+, Cu2+, Fe3+ was tested. As the optically active substituents necessarily possess interesting electronic properties, a second focus of this work was to utilize the developed ligand systems for MoCo and WCo models and to investigate their potential catalytic activity in the model oxotransfer reaction between DMSO and PPh3 in ...",
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<|eot_id|> |
3A836421574.jsonld | Document
### Text: {
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"title": "A history of fear : British apocalyptic fiction, 1895 - 2011",
"abstract": "Zusammenfassung: The idea of the end of the world has a long tradition in the history of civilization. Secularized speculations about the end of the world have been a part of public discourse in Britain ever since the 19th century. This study investigates fiction about the potential end of humankind, written and produced by British writers and filmmakers from the 1890s to the beginning of the 21st century. Martin Hermann argues that British apocalyptic fiction is deeply embedded in the cultural context of its respective era. Applying ideas from Michel Foucault\u2019s The Archaeology of Knowledge and analyzing works by H. G. Wells, John Wyndham, John Brunner, Stephen Baxter and other, less remembered authors of speculative fiction, Hermann traces a history of fear in British culture, identifying the discursive formations that have shaped the apocalyptic discourse in Britain over the last 120 years. He contends that these formations run alongside the great historical divides of the 20th and 21st century.",
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<|eot_id|> |
3A837330882.jsonld | Document
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"title": "Terahertz metamaterials : from fundamental coupling mechanisms to new terahertz metasurfaces and functional emitters",
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<|eot_id|> |
3A837340357.jsonld | Document
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<|eot_id|> |
3A838588832.jsonld | Document
### Text: {
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"title": "Thermoplastische, biobasierte, polyethylen-\u00e4hnliche Polyester und isocyanatfreie Darstellung biobasierter Polymere unter vollst\u00e4ndiger stofflicher Nutzung",
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"Zusammenfassung: In this work novel bio-based thermoplastic and thermoset materials were synthesized with the use of renewable raw materials and carbon dioxide and their basic structure-property relationships were elucidated. An important task was the polycondensation of crystallizable long-chain diesters which are accessible by alkoxycarbonylation of unsaturated fatty acid esters to produce polyethylene-like polyesters with variable oligo ethylene segments. The polyesters were processed by injection molding, film extrusion and electrospinning. As an alternative to polycondensation which needs several hours of reaction time high molecular weight polyesters, polyurea-amides and polyurea-ester-amides were obtained by reactive extrusion within minutes by isocyanate-free polyaddition reactions in polymer melts. Polyaddition reactions of purified limonene dicarbonate were in the focus to make isocyanate-free linear high molecular weight polyurethanes, polyurethane networks and coatings accessible by the use of CO2.Together with the group of Prof. Mecking biobased \u03b1, \u03c9-oligoethylene diesters with variable and crystallizable hydrocarbon segments were obtained by transesterification of fats with methanol and subsequent isomerizing alkoxycarbonylation in one step and successfully used in the polyester synthesis. These bio-based materials combine typical properties of polyethylene and polyesters. For the first time, high molecular weight and readily processable homo- and copolyesters became accessible by polycondensation with diols. It was possible to control their material properties by the oligo ethylene segment length. The polyethylene-like polyesters were obtained with melting temperatures above 100 \u00b0C, Young\u00b4s modules up to 400 MPa and values for the elongation at break of about 600 %. Electrospun nonwovens made from polyester solutions were biocompatible, biodegradable and suitable for cell colonization which was investigated in cooperation with Prof. Shastri\u00b4s group. By melt compounding films and phase-separated blends with other polyesters and polyolefins have been made available. Already 5 wt% polyester blended with PLA was sufficient to reduce the hydrophilicity and to enhance the resistance to hydrolysis. Polyesters were loaded by melt compounding with dyes and its function as a carrier for the controlled release of dyes were demonstrated.As an alternative to polyester synthesis by polycondensation isocyanate-free reactive extrusion methods have been ...",
"Zusammenfassung: Durch die Nutzung von erneuerbaren Rohstoffen und Kohlendioxid wurden in der vorliegenden Arbeit neuartige thermo- und duroplastische bio-basierte Werkstoffe synthetisiert und deren grundlegenden Struktur/Eigenschafts-Beziehungen aufgekl\u00e4rt. Wichtiges Ziel war die Polykondensation von kristallisationsf\u00e4higen langkettigen Dicarbons\u00e4ureestern, zug\u00e4nglich durch Alkoxycarbonylierung von unges\u00e4ttigten Fetts\u00e4ureestern, um polyethylen\u00e4hnliche Polyester mit variablen Oligoethylensegmenten herzustellen und durch Spritzguss, Folienextrusion und Elektrospinnen zu verarbeiten. Als Alternative zur Polykondensation, die mehrere Stunden dauerte, wurden hochmolekulare Polyester, Polyharnstoffamide und Polyharnstoffesteramide auch durch Reaktionsextrusion innerhalb von Minuten durch isocyanatfreie Polyadditionsreaktionen in Polymerschmelzen gewonnen. Schwerpunkt bei den Duroplastsystemen und der Nutzung von Kohlendioxid waren Polyadditionsreaktionen von aufgereinigtem Limonendicarbonat, welche isocyanatfrei lineare hochmolekulare Polyurethane und Polyurethan-Netzwerke sowie Lacke zug\u00e4nglich machten.Durch Umesterung von Fetten mit Methanol und anschlie\u00dfende isomerisierende Alkoxycarbonylierung wurden gemeinsam mit der Gruppe von Prof. Mecking in einem Schritt biobasierte \u03b1,\u03c9-Oligoethylen-diester mit variablen und kristallisationsf\u00e4higen Kohlenwasserstoffsegmenten gewonnen und erfolgreich in der Polyestersynthese eingesetzt. Diese so erhaltenen bio-basierten Werkstoffe kombinierten die f\u00fcr Polyethylen und Polyester typischen Eigenschaften. Erstmals gelang es, hochmolekulare und gut verarbeitbare Homo- und Copolyester durch Polykondensationsreaktionen mit Diolen zug\u00e4nglich zu machen und deren Materialeigenschaften \u00fcber die Oligoethylensegmenl\u00e4ngen zu steuern. Es wurden polyethylen\u00e4hnliche Polyester mit Schmelztemperaturen \u00fcber 100 \u00b0C, E-Module um 400 MPa und Bruchdehnungen von \u00fcber 600 % erhalten. Die durch Elektrospinnen von Polyesterl\u00f6sungen erzeugten Polyestervliese waren biokompatibel, bioabbaubar und f\u00fcr die Zellbesiedelung geeignet, was in Zusammenarbeit mit der Gruppe um Prof. Shastri untersucht wurde. Durch Schmelzcompoundierung konnten Folien sowie phasenseparierte Blends mit anderen Polyestern und Polyolefinen zug\u00e4nglich gemacht werden. Bereits 5 Gew.-% Polyester im Blend mit Polymilchs\u00e4ure reichten aus, die Hydrophilie zu reduzieren und die Hydrolysebest\u00e4ndigkeit zu steigern. Polyester wurden durch Schm ..."
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<|eot_id|> |
3A838966365.jsonld | Document
### Text: {
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<|eot_id|> |
3A839151047.jsonld | Document
### Text: {
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"(classificationName=bk, id=106421433)42.15 - Zellbiologie",
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"title": "Ableitung humaner mesenchymaler Zelltypen aus induzierten pluripotenten Stammzellen",
"abstract": "Mesenchymale Stammzellen, induzierte pluripotente Stammzellen, iPS-MSC, embryoid Body-Methode, Monolayer-Methode. - Mesenchymal stem cells, induced pluripotent stem cells, embryoid body-method, monolayer-method",
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<|eot_id|> |
3A839316232.jsonld | Document
### Text: {
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"abstract": "In this thesis we utilize resolved stellar populations to improve our understanding of galaxy formation and evolution. In the first part we improve a method for metallicity determination of faint old stellar systems, in the second and third part we analyze the individual history of six nearby disk galaxies outside the Local Group. A New Calibration of the Color Metallicity Relation of Red Giants for HST data: It is well known, that the color distribution of stars on the the Red Giant Branch (RGB) can be used to determine metallicities of old stellar populations that have only shallow photometry. Based on the largest sample of globular clusters ever used for such studies, we quantify the relation between metallicity and color in the widely used HST ACS filters F606W and F814W. We use a sample of globular clusters from the ACS Globular Cluster Survey and measure their RGB color at given absolute magnitudes to derive the color-metallicity relation. We find a clear relation between metallicity and RGB color; we investigate the scatte\u2026",
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<|eot_id|> |
3A840214162.jsonld | Document
### Text: {
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"title": "\u00dcber den strukturellen Aufbau und die Dynamik von Saccharid/Proteinmischungen in L\u00f6sung und im Festk\u00f6rper",
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"In this thesis the influence of saccharides on proteins is investigated. Therefore the aggregation process of saccharides and proteins in solution is systematically investigated in dependence of the experimental conditions. The method of field-gradient NMR was used to measure the self diffusion coefficient. The results are interpreted in connection with the literature data. Furthermore the influence of a solid Trehalose matrix on the molecular dynamics of the cold-shock protein Csp was investigated. Several solid-state NMR experiments were used for the investigation. By comparing the molecular dynamics of the protein in dependence of the properties of the surrounding matrix (water content, crystalline or glassy Trehalose) one can find out information about the distribution of water molecules in the system.",
"Die Arbeit befasst sich mit dem Einfluss von Sacchariden auf Proteine. Daf\u00fcr wird der Anlagerungsprozess von Sacchariden an Proteinen in L\u00f6sung systematisch in Abh\u00e4ngigkeit von den experimentellen Bedingungen charakterisiert. Dies geschieht \u00fcber die Messung des Selbstdiffusionskoeffizienten mit Hilfe der Feldgradienten-NMR. Die Ergebnisse werden in den Kontext der bereits vorhandenen Literatur eingeordnet. Weiterhin wird der Einfluss einer Trehalosematrix auf die molekularen dynamischen Eigenschaften des K\u00e4lteschockproteins Csp untersucht. Hierf\u00fcr werden mehrere Festk\u00f6rper-NMR Experimente verwendet. Durch den Vergleich der molekularen dynamischen Eigenschaften des Proteins in Abh\u00e4ngigkeit vom Zustand der umgebenden Matrix (Wassergehalt, kristalline oder amorphe Trehalosematrix) k\u00f6nnen Aussagen \u00fcber die Verteilung von Wassermolek\u00fclen in den Proben gewonnen werden.",
"solid-state NMR; molecular dynamic; glassy Trehalose; diffusion; field-gradient NMR; aggregation process; protein; dehydration",
"Festk\u00f6rper-NMR; molekulare Dynamik; amorphe Trehalose; Diffusion; Feldgradienten-NMR; Anlagerungsprozess; Protein; Wassermangel"
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<|eot_id|> |
3A842127143.jsonld | Document
### Text: {
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"title": "Modellierung der Bedingungen beim Schneiden insbesondere in einer Wolfmaschine mit dem Ziel der Optimierung des Zerkleinerungsprozesses sowie der Erh\u00f6hung der Produktqualit\u00e4t",
"abstract": [
"Comminution processes are essential for sausage production. Until now, mincers are not suited for producing fine comminuted emulsified meat batters at high quality, therefore choppers are used. The aim of this work was to develop a continuous process for the production of fine comminuted emulsified meat battersfor high-quality cooked sausages, based on the mincing principle. At first, the operation principles of mincing (fixed knife cut, rotating shear cut) were described and the necessary works (compression, friction, disintegration, shift) were derivedby using mathematical models. Next, the influences on works or length of meat pieces by raw material (e.g. type of tissue, temperature, sample size) and technology (drill-hole diameter, pressure) were deduced. Based on this, the new process for production of fine comminuted emulsified meat batter were developed (and patented). As a result, the sensory and nutritional quality of the cooked sausages was comparable with those from chopper, but more cost-effective atproduction. A prerequisite was, that sample size, drill-hole diameter, pressure and knife rotation speed were tool-specific adapted on each other.",
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"Zerkleinerung; Wolf; Feinbr\u00e4t; Br\u00fchwurst; Rohstoff; F\u00f6rderdruck; Bohrungsdurchmesser; Arbeit; Z\u00e4pfchenl\u00e4nge; Qualit\u00e4t",
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<|eot_id|> |
3A843605421.jsonld | Document
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"title": "Quantum key security : theory and analysis of experimental realisations",
"abstract": "Continuous variable quantum cryptography, hybrid reconciliation, runtime analysis, asymmetric protocol. - Quanten-Schl\u00fcsselerzeugung, hybride Fehlerkorrektur, Laufzeitanalyse, asymmetrische Protokolle",
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"@id": "http://purl.org/dc/terms/language",
"@type": "@id"
},
"license": "http://purl.org/dc/terms/license",
"umbel": "http://umbel.org/umbel#",
"rdau": "http://www.rdaregistry.info/Elements/u/#",
"owl": "http://www.w3.org/2002/07/owl#",
"dcterms": "http://purl.org/dc/terms/",
"bibo": "http://purl.org/ontology/bibo/",
"rdam": "http://www.rdaregistry.info/Elements/m/#",
"gnd": "http://d-nb.info/gnd/",
"isbd": "http://iflastandards.info/ns/isbd/elements/",
"rda": "http://rdvocab.info/",
"doi": "https://doi.org/"
}
}
<|eot_id|> |
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