Dataset Viewer
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stringdate 1300-01-01 00:00:00
1351-01-01 00:00:00
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1300 | https://doi.org/10.1002 anie.202214706 | {
"title": "[{\"type\": \"Table\", \"index\": \"S7\", \"text\": \"Dicarbonylation of \\\\textit{trans}-1,2-cyclohexanediol \\\\textbf{\\\\refiden{1a}}:Investigation of the catalyst loading.\", \"bbox\": [16.69879722595215, 11.80801010131836, 728.8491764068604, 33.081504821777344]}]",
"annotations": "[]",
"reactions": "[{\"id\": \"1300-rea1\", \"reactants\": [{\"id\": \"1300-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]OC1CCCCC1O[#smiles#]\"}], \"bbox\": [23.50978660583496, 96.7687759399414, 107.20923805236816, 160.46508026123047]}, {\"id\": \"1300-rea1-rea-sub2\", \"text\": \"\\\\iden{2a}\", \"maps\": [{\"identifier\": \"2a\", \"smiles\": \"[#smiles#]C(C=C)CCCCC[#smiles#]\"}], \"bbox\": [134.20550537109375, 116.03142547607422, 100.92387390136719, 140.09827423095703]}], \"conditions\": [{\"id\": \"1300-rea1-con1\", \"text\": \"PdCl_2/\\\\refiden{L16}/PTSA(\\\\textit{\\\\textbf{x}}/\\\\textit{\\\\textbf{y}}/\\\\textit{\\\\textbf{z}} mol%)\", \"maps\": [], \"bbox\": [269.30658437224434, 89.8828397035655, 156.0199527435022, 53.1688107114728]}, {\"id\": \"1300-rea1-con2\", \"text\": \"toluene(2.0 mL)CO(40 bar),100°C£¬20 h\", \"maps\": [], \"bbox\": [238.7998809814453, 146.5381317138672, 226.6211700439453, 54.040435791015625]}], \"products\": [{\"id\": \"1300-rea1-pro-sub1\", \"text\": \"monoester\\\\iden{3}\", \"maps\": [{\"identifier\": \"3\", \"smiles\": \"[#smiles#]O=C(CCCCCCCC)OC1CCCCC1O[#smiles#]\"}], \"bbox\": [466.2926330566406, 64.60586547851562, 174.13998413085938, 187.07872009277344]}, {\"id\": \"1300-rea1-pro-sub2\", \"text\": \"diester\\\\iden{n-4aa}\", \"maps\": [{\"identifier\": \"n-4aa\", \"smiles\": \"[#smiles#]O=C(CCCCCCCC)OC1C(OC(=O)CCCCCCCC)CCCC1[#smiles#]\"}], \"bbox\": [640.6166395048249, 64.60586411942268, 210.93200315043316, 184.78340771856125]}, {\"id\": \"1300-rea1-pro-sub3\", \"text\": \"\\\\textit{\\\\textbf{iso}}\\\\textbf{-\\\\refiden{4aa} \\\\impIden{5a}\", \"maps\": [{\"identifier\": \"5a\", \"smiles\": \"[#smiles#]O=C(C(C(C)(C)C)C(C)C)OC1C(OC(=O)CCCCCCCC)CCCC1[#smiles#]\"}], \"bbox\": [376.8520812988281, 248.4412841796875, 288.9974060058594, 179.19363403320312]}, {\"id\": \"1300-rea1-pro-sub4\", \"text\": \"\\\\textit{\\\\textbf{iso}}\\\\textbf{-\\\\refiden{4aa} \\\\impIden{6a}\", \"maps\": [{\"identifier\": \"6a\", \"smiles\": \"[#smiles#]O=C(C(C(C)(C)C)C(C)C)OC1C(OC(=O)C(C(C)(C)C)C(C)C)CCCC1[#smiles#]\"}], \"bbox\": [586.0675659179688, 247.02066040039062, 268.133544921875, 181.23843383789062]}], \"text\": \"\", \"bbox\": [11.797297297297291, 57.00476947535773, 857.1828298887123, 384.2543720190779]}]",
"substances": "[]",
"tables": "[{\"id\": \"1300-tab1\", \"text\": \"\", \"bbox\": [25.52066834211726, 453.92687003373726, 823.4022235870361, 180.51510620117188], \"data\": [{\"id\": \"1300-tab1-c1\", \"text\": \"Entry\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [42.90368839851585, 463.0201151698789, 56.732894826066264, 31.06801383332197]}, {\"id\": \"1300-tab1-c2\", \"text\": \"\\\\textit{\\\\textbf{x}}mol%\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [147.58938718470955, 467.0724648003122, 77.67003458330501, 27.015664202888672]}, {\"id\": \"1300-tab1-c3\", \"text\": \"\\\\textit{\\\\textbf{y}}mol%\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [271.86144251799755, 467.0724648003122, 78.34542618837725, 29.04183901810535]}, {\"id\": \"1300-tab1-c4\", \"text\": \"\\\\textit{\\\\textbf{z}}mol%\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [377.22253290926346, 466.39707319524, 75.64385976808836, 26.340272597816465]}, {\"id\": \"1300-tab1-c5\", \"text\": \"Conversion\\\\textbf{\\\\refiden{1a}}/%\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [489.33753935125156, 456.26619911915674, 99.282565945616, 47.27741235505522]}, {\"id\": \"1300-tab1-c6\", \"text\": \"Yield \\\\textbf{\\\\refiden{3a}}/%(\\\\textit{n/iso})\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"6\", \"end_col\": \"6\", \"maps\": [], \"bbox\": [611.5834198693229, 454.9154159090123, 104.01030718112156, 47.27741235505522]}, {\"id\": \"1300-tab1-c7\", \"text\": \"Yield \\\\textbf{\\\\refiden{4a}}/%(\\\\textit{n/iso})\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"7\", \"end_col\": \"7\", \"maps\": [], \"bbox\": [731.1277339671054, 454.24002430394006, 108.0626568115548, 48.62819556519969]}, {\"id\": \"1300-tab1-c8\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [58.613324182717335, 512.7207976033311, 29.062935207905, 26.420850189004568]}, {\"id\": \"1300-tab1-c9\", \"text\": \"0.5\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [168.92037372181133, 506.7761063108051, 39.631275283506824, 29.062935207905014]}, {\"id\": \"1300-tab1-c10\", \"text\": \"2\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [300.36410341210893, 509.41819132970556, 25.099807679554317, 27.08137144372961]}, {\"id\": \"1300-tab1-c11\", \"text\": \"4\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [402.08437663977645, 506.7761063108051, 27.741892698454762, 33.02606273625571]}, {\"id\": \"1300-tab1-c12\", \"text\": \"99\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [519.6571599808467, 512.0602763486061, 36.328669009881196, 27.08137144372961]}, {\"id\": \"1300-tab1-c13\", \"text\": \"trace\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"6\", \"end_col\": \"6\", \"maps\": [], \"bbox\": [637.890464576642, 510.73923383915576, 57.46534916108499, 27.081371443729722]}, {\"id\": \"1300-tab1-c14\", \"text\": \"92(86/14)\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"7\", \"end_col\": \"7\", \"maps\": [], \"bbox\": [736.9862060546875, 508.80364990234375, 97.415771484375, 29.681396484375]}, {\"id\": \"1300-tab1-c15\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [57.35908126831055, 549.9009399414062, 25.115001678466797, 31.2034912109375]}, {\"id\": \"1300-tab1-c16\", \"text\": \"0.25\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [164.6686248779297, 549.9009399414062, 46.42469787597656, 28.92034912109375]}, {\"id\": \"1300-tab1-c17\", \"text\": \"1\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [294.80999755859375, 552.1841430664062, 29.68133544921875, 28.15923309326172]}, {\"id\": \"1300-tab1-c18\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [401.35847051291637, 552.1841337377992, 26.637120806907603, 28.1592419958738]}, {\"id\": \"1300-tab1-c19\", \"text\": \"99\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [521.606044441242, 546.8567095764178, 32.725605562772216, 31.964544968289147]}, {\"id\": \"1300-tab1-c20\", \"text\": \"trace\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"6\", \"end_col\": \"6\", \"maps\": [], \"bbox\": [635.7651336137033, 552.1841337377992, 53.27424161381521, 31.203484373806077]}, {\"id\": \"1300-tab1-c21\", \"text\": \"94(86/14)\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"7\", \"end_col\": \"7\", \"maps\": [], \"bbox\": [737.7472532744351, 549.90095195435, 96.65469549935051, 35.008787346221425]}, {\"id\": \"1300-tab1-c22\", \"text\": \"3\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [58.120142401049904, 594.8035270288515, 27.398181401390673, 29.681363184839824]}, {\"id\": \"1300-tab1-c23\", \"text\": \"0.1\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [166.9518074121295, 596.3256482178176, 47.18575685795062, 25.114999617941407]}, {\"id\": \"1300-tab1-c24\", \"text\": \"0.4\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [292.52679443359375, 594.8035278320312, 36.530914306640625, 28.9202880859375]}, {\"id\": \"1300-tab1-c25\", \"text\": \"0.8\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [396.0310463515348, 593.2814058398852, 35.769847940704494, 28.92030259035687]}, {\"id\": \"1300-tab1-c26\", \"text\": \"99\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [519.3228626577929, 595.5645876233345, 35.769847940704494, 29.681363184839824]}, {\"id\": \"1300-tab1-c27\", \"text\": \"trace\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"6\", \"end_col\": \"6\", \"maps\": [], \"bbox\": [635.7651336137033, 598.6088300012668, 59.36272636967976, 24.353939023458338]}, {\"id\": \"1300-tab1-c28\", \"text\": \"90(89/11)\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"7\", \"end_col\": \"7\", \"maps\": [], \"bbox\": [736.9861926799521, 595.5645876233345, 94.3715137159013, 30.442423779322894]}]}]",
"qa": [
{
"question": "What is the content of the cell at row 1 and column 4 in the picture?",
"answer": "zmol%",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"zmol%\" in the picture?",
"answer": "Row 1, Column 4",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "4 rows × 7 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Dicarbonylation of trans-1,2-cyclohexanediol 1a:Investigation of the catalyst loading.",
"unable_to_answer": false
},
{
"question": "When the concentration of 4a is at its highest, what are the respective concentrations of x, y, and z?",
"answer": "When the concentration of 4a is at its highest, the concentration of x is 0.25 mol%, y is 1 mol%, and z is 2 mol%.",
"unable_to_answer": false
}
]
} |
1301 | https://doi.org/10.1002 anie.202214706 | {
"title": "[{\"type\": \"Table\", \"index\": \"2\", \"text\": \"Palladium-catalyzed dicarbonylation of \\\\textit{trans-}1,2-cyclohexane-diol \\\\textbf{\\\\refiden{1a}} with 1-octene \\\\textbf{\\\\refiden{2a}}: Variation of reaction conditions.\", \"bbox\": [18.441215231108917, 4.410818088715734, 609.8974587605888, 53.49977708426217]}]",
"annotations": "[{\"text\": \"Reaction conditions: \\\\textbf{\\\\refiden{1a}} (1.0 mmol), \\\\textbf{\\\\refiden{2a}} (4.0 mmol), [Pd](1.0 mol%), \\\\textbf{\\\\refiden{L16}}(4.0 mol%), co-cat. acid (8.0 or 16 mol%), CO (40 bar), solvent (2.0 mL), 100°C, 20 h. The conversion of \\\\textbf{\\\\refiden{1a}}, yields of \\\\textbf{\\\\refiden{3}} and \\\\textbf{\\\\refiden{4aa}}, and ratios of isomers were determined by GC analysis using isooctane as the internal standard.\", \"bbox\": [20.47219643232728, 689.9212951283951, 592.0641997325014, 130.53945608559968]}]",
"reactions": "[{\"id\": \"1301-rea1\", \"reactants\": [{\"id\": \"1301-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]OC1CCCCC1O[#smiles#]\"}], \"bbox\": [20.457050323486328, 93.6474380493164, 78.5438346862793, 112.96849822998047]}, {\"id\": \"1301-rea1-rea-sub2\", \"text\": \"\\\\iden{2a}\", \"maps\": [{\"identifier\": \"2a\", \"smiles\": \"[#smiles#]C(C=C)CCCCC[#smiles#]\"}], \"bbox\": [106.49593353271484, 98.105224609375, 70.28527069091797, 109.82687377929688]}], \"conditions\": [{\"id\": \"1301-rea1-con1\", \"text\": \"Pd(CH_3CN)_2Cl_2/\\\\textbf{\\\\refiden{L16}}/PTSA (1.0/4.0/16 mol%)\", \"maps\": [], \"bbox\": [176.1753041049879, 92.65205589155015, 168.44231254733666, 32.719010350921494]}, {\"id\": \"1301-rea1-con2\", \"text\": \"toluene (2.0 mL) CO (40 bar), 100 °C, 20 h\", \"maps\": [], \"bbox\": [182.2343800958993, 130.21832703520076, 158.7477909618784, 36.96036354455947]}], \"products\": [{\"id\": \"1301-rea1-pro-sub1\", \"text\": \"\\\\iden{3} monoester\", \"maps\": [{\"identifier\": \"3\", \"smiles\": \"[#smiles#]O=C(CCCCCCCC)OC1CCCCC1O[#smiles#]\"}], \"bbox\": [350.0707702636719, 71.4452896118164, 122.43887329101562, 131.97577667236328]}, {\"id\": \"1301-rea1-pro-sub2\", \"text\": \"\\\\iden{n-4aa} diester\", \"maps\": [{\"identifier\": \"n-4aa\", \"smiles\": \"[#smiles#]O=C(CCCCCCCC)OC1C(OC(=O)CCCCCCCC)CCCC1[#smiles#]\"}], \"bbox\": [474.88775634765625, 72.05120086669922, 146.629638671875, 131.6395492553711]}], \"text\": \"\", \"bbox\": [12.729918479919434, 70.0372085571289, 621.1693725585938, 139.89051055908203]}]",
"substances": "[]",
"tables": "[{\"id\": \"1301-tab1\", \"text\": \"\", \"bbox\": [4.459360763202138, 336.76235361811496, 611.940298507463, 347.7611940298509], \"data\": [{\"id\": \"1301-tab1-c1\", \"text\": \"Entry\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [22.42139932269436, 339.61278788258744, 51.87186414511774, 22.848321111539917]}, {\"id\": \"1301-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [21.803877130490577, 427.91846136772836, 17.29062138170592, 24.083365495947533]}, {\"id\": \"1301-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [20.96358465440228, 455.9470976707913, 17.29818780889622, 21.74629324546953]}, {\"id\": \"1301-tab1-c4\", \"text\": \"3\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [20.96358465440228, 481.6472624154371, 17.29818780889622, 21.25205930807249]}, {\"id\": \"1301-tab1-c5\", \"text\": \"4\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [19.480882842211177, 505.86472534789186, 22.24052718286657, 23.228995057660654]}, {\"id\": \"1301-tab1-c6\", \"text\": \"5\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [20.96358465440228, 531.0706561551407, 18.286655683690295, 23.22899505766054]}, {\"id\": \"1301-tab1-c7\", \"text\": \"6\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [20.96358465440228, 557.2650548371835, 18.286655683690295, 19.275123558484324]}, {\"id\": \"1301-tab1-c8\", \"text\": \"7\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [19.480882842211177, 604.7115128272989, 21.2520593080725, 22.240527182866572]}, {\"id\": \"1301-tab1-c9\", \"text\": \"8\", \"start_row\": \"9\", \"end_row\": \"9\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [21.457818591799303, 632.3886133215328, 17.792421746293257, 20.263591433278407]}, {\"id\": \"1301-tab1-c10\", \"text\": \"9\", \"start_row\": \"10\", \"end_row\": \"10\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [18.986648904814125, 655.6176083791934, 18.28665568369029, 21.746293245469587]}, {\"id\": \"1301-tab1-c11\", \"text\": \"Variation of \\\"standard conditions\\\"\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [81.26012501684052, 339.30788844509107, 111.69686985172989, 74.62932454695232]}, {\"id\": \"1301-tab1-c12\", \"text\": \"Pd(acac)_2 as [Pd]\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [82.24859289163459, 430.74116686354256, 146.78747940691937, 25.700164744645804]}, {\"id\": \"1301-tab1-c13\", \"text\": \"Pd_2(dba)_3 as [Pd]\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [83.23706076642867, 456.44133160818836, 146.78747940691935, 24.217462932454737]}, {\"id\": \"1301-tab1-c14\", \"text\": \"PdCl_2 as [Pd]\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [83.23706076642867, 481.1530284780401, 114.16803953871505, 24.217462932454737]}, {\"id\": \"1301-tab1-c15\", \"text\": \"CF_3SO_3H as acid\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [84.22552490234375, 505.3704528808594, 144.31631469726562, 25.205963134765625]}, {\"id\": \"1301-tab1-c16\", \"text\": \"H_2SO_4 as acid\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [82.24859289163459, 531.0706561551407, 123.55848434925872, 22.240527182866572]}, {\"id\": \"1301-tab1-c17\", \"text\": \"PdCl_2 as [Pd], and 8.0 mol% PTSA\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [82.74282682903163, 555.7823530249924, 174.46457990115334, 46.95222405271829]}, {\"id\": \"1301-tab1-c18\", \"text\": \"Heptane as solvent\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [82.74282682903163, 604.2172788899018, 167.0510708401978, 25.20593080724882]}, {\"id\": \"1301-tab1-c19\", \"text\": \"MeCN as solvent\", \"start_row\": \"9\", \"end_row\": \"9\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [83.23706076642867, 630.9059115093416, 149.25864909390452, 22.240527182866572]}, {\"id\": \"1301-tab1-c20\", \"text\": \"THF as solvent\", \"start_row\": \"10\", \"end_row\": \"10\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [83.7312947038257, 655.6176083791934, 131.46622734761127, 24.711696869851835]}, {\"id\": \"1301-tab1-c21\", \"text\": \"Conversion \\\\textbf{\\\\refiden{1a}} [%]\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [265.60938366593456, 335.3540169459148, 130.97199341021422, 59.30807248764421]}, {\"id\": \"1301-tab1-c22\", \"text\": \"99\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [267.58631941552267, 428.7642311139544, 29.654036243822134, 25.20593080724882]}, {\"id\": \"1301-tab1-c23\", \"text\": \"99\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [269.56325516511083, 456.44133160818836, 26.688632619439886, 21.25205930807249]}, {\"id\": \"1301-tab1-c24\", \"text\": \"99\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [268.57478729031675, 481.1530284780401, 26.194398682042845, 23.228995057660654]}, {\"id\": \"1301-tab1-c25\", \"text\": \"99\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [270.5517230399049, 506.85319322268595, 24.21746293245468, 22.240527182866572]}, {\"id\": \"1301-tab1-c26\", \"text\": \"99\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [271.54019091469894, 531.5648900925377, 22.734761120263613, 20.757825370675505]}, {\"id\": \"1301-tab1-c27\", \"text\": \"99\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [272.034424852096, 555.7823530249924, 22.734761120263613, 22.734761120263556]}, {\"id\": \"1301-tab1-c28\", \"text\": \"96\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [270.0574891025079, 604.7115128272989, 25.700164744645804, 23.72322899505764]}, {\"id\": 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\"1301-tab1-c33\", \"text\": \"trace\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [404.98335401189837, 455.9470976707913, 50.90609555189462, 21.25205930807249]}, {\"id\": \"1301-tab1-c34\", \"text\": \"trace\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [407.4545236988836, 481.6472624154371, 54.3657331136738, 20.757825370675505]}, {\"id\": \"1301-tab1-c35\", \"text\": \"5 (72/28)\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [405.97182188669245, 503.8877895983037, 85.9967051070841, 25.700164744645804]}, {\"id\": \"1301-tab1-c36\", \"text\": \"22 (93/7)\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [406.96028976148654, 533.0475919047287, 85.99670510708404, 25.20593080724882]}, {\"id\": \"1301-tab1-c37\", \"text\": \"trace\", 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(\\\\textit{n/iso})\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [513.714820239246, 336.8367187581059, 89.95057660626037, 56.34266886326196]}, {\"id\": \"1301-tab1-c42\", \"text\": \"92 (87/13)\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [514.2090541766431, 433.2123365505277, 93.4102141680396, 20.757825370675505]}, {\"id\": \"1301-tab1-c43\", \"text\": \"89 (87/13)\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [512.7263523644519, 456.44133160818836, 95.88138385502486, 22.734761120263613]}, {\"id\": \"1301-tab1-c44\", \"text\": \"93 (87/13)\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [516.1859899262313, 482.6357302902312, 91.43327841845144, 21.25205930807249]}, {\"id\": \"1301-tab1-c45\", \"text\": \"89 (79/21)\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [515.1975220514372, 506.85319322268595, 91.92751235584842, 23.72322899505764]}, {\"id\": \"1301-tab1-c46\", \"text\": \"71 (89/11)\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [516.1859899262313, 533.0475919047287, 88.46787479406919, 22.240527182866572]}, {\"id\": \"1301-tab1-c47\", \"text\": \"93 (90/10)\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [515.6917559888342, 555.7823530249924, 89.95057660626037, 24.71169686985172]}, {\"id\": \"1301-tab1-c48\", \"text\": \"41 (94/6)\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [513.714820239246, 606.688448576887, 85.50247116968706, 22.734761120263556]}, {\"id\": \"1301-tab1-c49\", \"text\": \"5 (78/22)\", \"start_row\": \"9\", \"end_row\": \"9\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [513.220586301849, 631.8943793841357, 85.50247116968706, 23.72322899505764]}, {\"id\": \"1301-tab1-c50\", \"text\": \"74 (76/24)\", \"start_row\": \"10\", \"end_row\": \"10\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [515.1975220514372, 656.6060762539875, 93.4102141680396, 24.217462932454737]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "Reaction conditions: 1a (1.0 mmol), 2a (4.0 mmol), [Pd](1.0 mol%), L16(4.0 mol%), co-cat. acid (8.0 or 16 mol%), CO (40 bar), solvent (2.0 mL), 100℃, 20 h. The conversion of 1a, yields of 3 and 4aa, and ratios of isomers were determined by GC analysis using isooctane as the internal standard.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 5 and column 5 in the picture?",
"answer": "89 (79/21)",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"89 (79/21)\" in the picture?",
"answer": "Row 5, Column 5",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "10 rows × 5 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Palladium-catalyzed dicarbonylation of trans-1,2-cyclohexane-diol 1a with 1-octene 2a: Variation of reaction conditions.",
"unable_to_answer": false
},
{
"question": "What is the highest yield of 4aa?",
"answer": "The highest yield of 4aa is 93%.",
"unable_to_answer": false
}
]
} |
1302 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"1\", \"text\": \"Selected examples of the optimization of the copper-catalyzed silylation of 2\\\\textit{H}-azirines.\\\\refmark{[a]}\", \"bbox\": [23.70904289661341, 12.072020602149939, 730.116003664295, 66.7844057739899]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]}All reactions were performed on a 0.20 mmol scale; MeOH was used as the proton source except in entries l and 8. \\\\mark{[b]} Determined by ^1H NMR spectroscopy with CH_2Br_2 as an internal standard. \\\\mark{[c]}Determined by HPLC analysis on a chiral stationary phase. \\\\mark{[d]}93 % yield and 92% \\\\textit{ee} were obtained on a 1.0-mmol scale. \\\\mark{[e]} Isolated yield after purification by flash chromatography on silica gel.\", \"bbox\": [25.514026836450977, 618.8707060207151, 723.7985598748635, 189.52331368294426]}]",
"reactions": "[{\"id\": \"1302-rea1\", \"reactants\": [{\"id\": \"1302-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [29.34502805590959, 139.87722766501398, 114.44942012142103, 136.9423697406598]}], \"conditions\": [{\"id\": \"1302-rea1-con1\", \"text\": \"Cu(CH_3CN)_4PF_6(3.0 mol%)\", \"maps\": [], \"bbox\": [156.26747743393253, 88.43444589326391, 255.21384973347108, 26.34465545635831]}, {\"id\": \"1302-rea1-con2\", \"text\": \"(\\\\textit{R,R})-Ph-BPE(\\\\textbf{\\\\refiden{L1}}, 3.6 mol%)\", \"maps\": [], \"bbox\": [145.83938464912404, 113.68140737227395, 271.679259393695, 24.69811449033591]}, {\"id\": \"1302-rea1-con3\", \"text\": \"LiO\\\\textit{t}Bu (40 mol%)\", \"maps\": [], \"bbox\": [201.82177749388543, 136.18413390791335, 166.3006375682618, 24.149267501661768]}, {\"id\": \"1302-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [153.5232391357422, 159.23570251464844, 256.31153869628906, 24.149261474609375]}, {\"id\": \"1302-rea1-con5\", \"text\": \"MeOH:H_2O(1:1, 2.0 equiv)\", \"maps\": [], \"bbox\": [161.20710033199973, 190.51998578665234, 246.98114490335914, 24.69811449033591]}, {\"id\": \"1302-rea1-con6\", \"text\": \"THF\", \"maps\": [], \"bbox\": [259.99955829334334, 214.66925328831414, 49.945075969345964, 20.856185569616997]}, {\"id\": \"1302-rea1-con7\", \"text\": \"0 °C to RT for 17 h\", \"maps\": [], \"bbox\": [190.8448377204028, 233.87889789190874, 180.0218122851151, 27.44234943370654]}], \"products\": [{\"id\": \"1302-rea1-pro-sub1\", \"text\": \"(\\\\textit{S})-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"3aa\", \"smiles\": \"[#smiles#]C[Si@@](C2=CC=CC=C2)(C)[C@]3(NC3)[C@@]1=CC=CC=C1[#smiles#]\"}], \"bbox\": [426.9409904430427, 118.70739272925978, 130.32679632323658, 162.08154872686794]}], \"text\": \"\", \"bbox\": [21.001566986857064, 83.69296785887714, 538.7877060415132, 201.25570929188848]}]",
"substances": "[]",
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\"end_col\": \"3\", \"maps\": [], \"bbox\": [545.1591959277499, 364.87385110516027, 97.6277434657344, 32.88513464108951]}, {\"id\": \"1302-tab1-c21\", \"text\": \"79\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [550.2974982154202, 399.81430666131786, 32.885134641089394, 23.122360294516056]}, {\"id\": \"1302-tab1-c22\", \"text\": \"31\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [553.8943098167894, 428.5887994722712, 26.71917189588521, 26.71917189588521]}, {\"id\": \"1302-tab1-c23\", \"text\": \"45\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [552.3528191304882, 456.8494620544575, 29.80215326848736, 28.260662582186285]}, {\"id\": \"1302-tab1-c24\", \"text\": \"85\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [552.3528191304882, 487.67927578047886, 31.34364395478849, 26.71917189588521]}, {\"id\": \"1302-tab1-c25\", \"text\": \"92\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [550.2974982154202, 517.9952592777332, 30.315983497254365, 24.663850980817188]}, {\"id\": \"1302-tab1-c26\", \"text\": \"46\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [554.4081400455564, 545.2282614023856, 29.288323039720353, 27.233002124652216]}, {\"id\": \"1302-tab1-c27\", \"text\": \"96\", \"start_row\": \"9\", \"end_row\": \"9\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [553.3804795880222, 578.6272262722421, 29.80215326848736, 25.177681209584193]}, {\"id\": \"1302-tab1-c28\", \"text\": \"ee [%]\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [668.4784508318355, 289.85463770517487, 53.43834379177042, 59.60430653697472]}, {\"id\": \"1302-tab1-c29\", \"text\": \"95\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [664.8816392304664, 365.90151156269434, 36.99577647122567, 27.74683235341928]}, {\"id\": \"1302-tab1-c30\", \"text\": \"88\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [670.5337717469037, 398.2728159750168, 26.205341667118205, 27.74683235341928]}, {\"id\": \"1302-tab1-c31\", \"text\": \"21\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [669.5061112893696, 426.01964832843606, 29.80215326848736, 29.288323039720353]}, {\"id\": \"1302-tab1-c32\", \"text\": \"38\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [670.5337717469037, 457.3632922832245, 27.233002124652216, 27.233002124652216]}, {\"id\": \"1302-tab1-c33\", \"text\": \"87\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [670.5337717469037, 485.6239548654108, 28.774492810953348, 26.205341667118205]}, {\"id\": \"1302-tab1-c34\", \"text\": \"89\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [671.5614322044377, 516.9675988201992, 28.774492810953348, 29.288323039720353]}, {\"id\": \"1302-tab1-c35\", \"text\": \"31\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [670.5337717469037, 549.8527334612887, 29.288323039720353, 24.15002075205018]}, {\"id\": \"1302-tab1-c36\", \"text\": \"95\", \"start_row\": \"9\", \"end_row\": \"9\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [668.9922810606025, 577.5995658147081, 28.26066258218634, 25.6915114383512]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a]All reactions were performed on a 0.20 mmol scale; MeOH was used as the proton source except in entries l and 8. [b] Determined by ^1H NMR spectroscopy with CH_2Br_2 as an internal standard. [c]Determined by HPLC analysis on a chiral stationary phase. [d]93 % yield and 92% ee were obtained on a 1.0-mmol scale. [e] Isolated yield after purification by flash chromatography on silica gel.",
"unable_to_answer": false
},
{
"question": "How many benzene rings are there in total in the reactants according to the table?",
"answer": "There is a total of 1 benzene ring in the reactants.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 4 and column 4 in the picture?",
"answer": "21",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"21\" in the picture?",
"answer": "Row 4, Column 4",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "9 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Selected examples of the optimization of the copper-catalyzed silylation of 2H-azirines.[a]",
"unable_to_answer": false
},
{
"question": "By replacing THF with toluene, how much did the yield increase or decrease?",
"answer": "By replacing THF with toluene, the yield decreased by 6%.",
"unable_to_answer": false
}
]
} |
1303 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"S3\", \"text\": \"Catalyst screening.\", \"bbox\": [12.82971835953239, 7.834441757355854, 312.61588069326893, 34.98589278516728]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} All reactions were performed on a 0.20 mmol scale. \\\\mark{[b]} Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. \\\\mark{[c]} Determined by HPLC analysis on a chiral stationary phase. n.d. = not detected.\", \"bbox\": [13.958295546150625, 704.1665659008465, 853.2043530834342, 100.44336960902865]}]",
"reactions": "[{\"id\": \"1303-rea1\", \"reactants\": [{\"id\": \"1303-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [121.17312827488905, 116.17785167271262, 134.30068520757763, 171.5437323659815]}], \"conditions\": [{\"id\": \"1303-rea1-con1\", \"text\": \"Catalyst (3.0 mol%)\", \"maps\": [], \"bbox\": [329.045675461985, 57.77515234766179, 195.22135444077225, 25.46365492705725]}, {\"id\": \"1303-rea1-con2\", \"text\": \"\\\\textit{(R,R)}-Ph-BPE (\\\\textbf{\\\\refiden{L1}}, 3.6 mol%)\", \"maps\": [], \"bbox\": [288.7282218274777, 81.82415977877142, 279.392880449656, 28.2929499189525]}, {\"id\": \"1303-rea1-con3\", \"text\": \"LiO\\\\textit{t}Bu (40 mol%)\", \"maps\": [], \"bbox\": [333.28961794982786, 110.11710969772392, 182.4895269772436, 21.92703618718818]}, {\"id\": \"1303-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [285.1916030876086, 132.75146963288591, 278.6855567016822, 24.04900743110963]}, {\"id\": \"1303-rea1-con5\", \"text\": \"MeOH (4.0 equiv)\", \"maps\": [], \"bbox\": [339.6555316815922, 190.75201696673855, 173.2943182535841, 24.756331179083418]}, {\"id\": \"1303-rea1-con6\", \"text\": \"THF\", \"maps\": [], \"bbox\": [398.3634027634186, 215.50834814582197, 54.46392859398361, 19.805064943266757]}, {\"id\": \"1303-rea1-con7\", \"text\": \"0 °C to RT, 17 h\", \"maps\": [], \"bbox\": [326.92370421806356, 236.72806058503636, 185.31882196913887, 27.585626170978685]}], \"products\": [{\"id\": \"1303-rea1-pro-sub1\", \"text\": \"\\\\textit{(S)}-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"3aa\", \"smiles\": \"[#smiles#][C@](C1=CC=CC=C1)([Si@@](C1=CC=CC=C1)(C)C)1NC1[#smiles#]\"}], \"bbox\": [597.4327010278114, 104.89207980652962, 161.38653768641677, 183.9580814187828]}], \"text\": \"\", \"bbox\": [86.18723548972179, 49.591797662232956, 676.0177347843612, 246.02982668278926]}]",
"substances": "[]",
"tables": "[{\"id\": \"1303-tab1\", \"text\": \"\", \"bbox\": [41.165917176755976, 320.01002356673484, 804.7960033305582, 379.5503746877604], \"data\": [{\"id\": \"1303-tab1-c1\", \"text\": \"\\\\textbf{Entry}\\\\refmark{[a]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [48.85315473229282, 332.9012135198161, 90.57888762769583, 30.192962542565283]}, {\"id\": \"1303-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [83.9378433227539, 384.54705810546875, 23.712133407592773, 27.809326171875]}, {\"id\": \"1303-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [79.84066892071509, 430.63106596022476, 24.63110102156641, 31.78206583427925]}, {\"id\": \"1303-tab1-c4\", \"text\": \"3\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [79.84066892071509, 479.0987163575006, 24.63110102156641, 31.78206583427925]}, {\"id\": \"1303-tab1-c5\", \"text\": \"4\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [78.25156562900112, 528.3609184006334, 25.425652667423392, 26.22020431328042]}, {\"id\": \"1303-tab1-c6\", \"text\": \"5\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [80.63522056657206, 566.4993974017685, 23.83654937570944, 30.987514188422324]}, {\"id\": \"1303-tab1-c7\", \"text\": \"6\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [76.66246233728717, 620.5289093200432, 27.80930760499433, 27.014755959137347]}, {\"id\": \"1303-tab1-c8\", \"text\": \"7\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [80.63522056657206, 663.4346981963203, 24.631101021566423, 28.603859250851315]}, {\"id\": \"1303-tab1-c9\", \"text\": \"\\\\textbf{Catalyst}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [299.13692317724184, 328.9284552905312, 96.93530079455172, 34.165720771850204]}, {\"id\": \"1303-tab1-c10\", \"text\": \"(Ph_3P)_2CuBH_4\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [269.73851228053354, 384.5470705005199, 150.17026106696943, 30.192962542565283]}, {\"id\": \"1303-tab1-c11\", \"text\": \"CuCN\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [311.84974951095353, 433.0147208977957, 65.94778660612945, 25.425652667423435]}, {\"id\": \"1303-tab1-c12\", \"text\": \"CuI\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [321.38436926123734, 477.50961306578665, 43.700340522133956, 28.603859250851315]}, {\"id\": \"1303-tab1-c13\", \"text\": \"CuTc\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [309.46609457338263, 523.5936085254916, 65.15323496027241, 27.809307604994274]}, {\"id\": \"1303-tab1-c14\", \"text\": \"Cu(acac)_2\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [285.62954519767317, 572.0612589227674, 112.82633371169135, 29.398410896708356]}, {\"id\": \"1303-tab1-c15\", \"text\": \"Cu(NO_3_)2\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [292.780510010386, 617.3507027366153, 100.1135073779796, 30.192962542565283]}, {\"id\": \"1303-tab1-c16\", \"text\": \"Cu(OTf)_2\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [298.3423715313849, 666.6129047797482, 93.75709421112379, 28.603859250851315]}, {\"id\": \"1303-tab1-c17\", \"text\": \"\\\\textbf{Yield/%}\\\\refmark{[b]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [558.1607597266177, 332.1066618739591, 103.29171396140748, 35.75482406356417]}, {\"id\": \"1303-tab1-c18\", \"text\": \"79\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [581.9973091023271, 381.36886391709197, 43.700340522133956, 33.37116912599322]}, {\"id\": \"1303-tab1-c19\", \"text\": \"31\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [589.1482739150399, 427.4528593767969, 34.16572077185026, 30.987514188422267]}, {\"id\": \"1303-tab1-c20\", \"text\": \"18\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [587.5591706233259, 477.50961306578665, 38.933030646992165, 30.192962542565283]}, {\"id\": \"1303-tab1-c21\", \"text\": \"38\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [589.1482739150399, 521.2099535879206, 33.37116912599322, 34.16572077185015]}, {\"id\": \"1303-tab1-c22\", \"text\": \"45\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [585.175515685755, 569.6776039851965, 44.49489216799088, 37.34392735527808]}, {\"id\": \"1303-tab1-c23\", \"text\": \"trace\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [579.6136541647562, 619.7343576741863, 60.385925085130566, 29.398410896708242]}, {\"id\": \"1303-tab1-c24\", \"text\": \"80\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [587.5591706233259, 666.6129047797482, 38.138479001135124, 27.809307604994274]}, {\"id\": \"1303-tab1-c25\", \"text\": \"\\\\textit{\\\\textbf{ee}}\\\\textbf{/%}\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [738.5239833361524, 331.31211022810214, 76.27695800227025, 32.576617480136235]}, {\"id\": \"1303-tab1-c26\", \"text\": \"88\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [752.031361315721, 382.95796720880594, 42.90578887627703, 27.80930760499433]}, {\"id\": \"1303-tab1-c27\", \"text\": \"21\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [756.7986711908629, 430.63106596022476, 30.192962542565283, 27.809307604994387]}, {\"id\": \"1303-tab1-c28\", \"text\": \"57\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [757.59322283672, 477.50961306578665, 34.16572077185015, 30.987514188422267]}, {\"id\": \"1303-tab1-c29\", \"text\": \"29\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [757.59322283672, 523.5936085254916, 34.16572077185015, 27.809307604994274]}, {\"id\": \"1303-tab1-c30\", \"text\": \"38\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [756.004119545006, 569.6776039851965, 38.93303064699205, 33.37116912599322]}, {\"id\": \"1303-tab1-c31\", \"text\": \"n.d.\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [748.8531547322931, 617.3507027366153, 44.494892167991, 30.987514188422324]}, {\"id\": \"1303-tab1-c32\", \"text\": \"49\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [755.209567899149, 663.4346981963203, 38.93303064699205, 29.398410896708242]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] All reactions were performed on a 0.20 mmol scale. [b] Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. [c] Determined by HPLC analysis on a chiral stationary phase. n.d. = not detected.",
"unable_to_answer": false
},
{
"question": "Is the number of benzene rings in the reactants and products the same in the table?",
"answer": "The number of benzene rings in the reactants and products is the same.",
"unable_to_answer": false
},
{
"question": "Which catalyst has the largest absolute difference between its yield (%) and ee (%) values?",
"answer": "Cu(OTf)_2",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 4 and column 4 in the picture?",
"answer": "57",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"57\" in the picture?",
"answer": "Row 4, Column 4",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "8 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Catalyst screening.",
"unable_to_answer": false
},
{
"question": "What catalyst is used when the yield is highest?",
"answer": "When the yield is highest, the catalyst used is Cu(OTf)_2.",
"unable_to_answer": false
}
]
} |
1304 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"S4\", \"text\": \"Solvent screening.\", \"bbox\": [13.379146038606184, 5.329133986795248, 329.7867757915142, 42.38638811113505]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} All reactions were performed on a 0.20 mmol scale. \\\\mark{[b]} Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. \\\\mark{[c]} Determined by HPLC analysis on a chiral stationary phase. \\\\mark{[d]}MeOH:H_2O (1:1, 2.0 equiv) as proton source. \\\\mark{[e]} Isolated yield after flash chromatography on silica gel. n.d.= not detected.\", \"bbox\": [16.480589071128232, 680.409900732434, 941.8048675425374, 130.26060736592717]}]",
"reactions": "[{\"id\": \"1304-rea1\", \"reactants\": [{\"id\": \"1304-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [132.26779561861912, 135.5897413527225, 144.73400818436357, 181.95132457462853]}], \"conditions\": [{\"id\": \"1304-rea1-con1\", \"text\": \"Cu(CH_3CN)_4PF_6 (3.0 mol%)\", \"maps\": [], \"bbox\": [321.5034560219426, 70.47365333942163, 291.6749679806462, 31.42165931407429]}, {\"id\": \"1304-rea1-con2\", \"text\": \"(\\\\textit{R,R})-Ph-BPE(\\\\textbf{\\\\refiden{L1}}, 3.6 mol%)\", \"maps\": [], \"bbox\": [315.3557400691889, 101.89531265349592, 308.7519567382953, 25.273943361320633]}, {\"id\": \"1304-rea1-con3\", \"text\": \"LiO\\\\textit{t}Bu (40 mol%)\", \"maps\": [], \"bbox\": [361.8051494899944, 126.48617646451059, 200.8253877899532, 27.32318201223852]}, {\"id\": \"1304-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [314.67266051888294, 153.12627892644315, 299.1888430340118, 27.323182012238533]}, {\"id\": \"1304-rea1-con5\", \"text\": \"MeOH (4.0 equiv)\", \"maps\": [], \"bbox\": [372.05134274458385, 216.65267710489772, 191.9453536359756, 28.006261562544495]}, {\"id\": \"1304-rea1-con6\", \"text\": \"solvent\", \"maps\": [], \"bbox\": [423.2823090175311, 243.2927795668303, 89.48342109008121, 23.907784260708695]}, {\"id\": \"1304-rea1-con7\", \"text\": \"0 °C to RT, 17 h\", \"maps\": [], \"bbox\": [380.2482973482554, 267.200563827539, 178.9668421801623, 28.006261562544466]}], \"products\": [{\"id\": \"1304-rea1-pro-sub1\", \"text\": \"(\\\\textit{S})-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"3aa\", \"smiles\": \"[#smiles#][C@](C1=CC=CC=C1)([Si@@](C1=CC=CC=C1)(C)C)1NC1[#smiles#]\"}], \"bbox\": [663.6483685240682, 114.913454469242, 162.30885203532205, 202.62761145810904]}], \"text\": \"\", \"bbox\": [126.06490955357495, 59.08747988384461, 712.2980831359037, 264.6564721085506]}]",
"substances": "[]",
"tables": "[{\"id\": \"1304-tab1\", \"text\": \"\", \"bbox\": [43.05632201516613, 352.7174019297141, 867.3702347620076, 320.4824466939479], \"data\": [{\"id\": \"1304-tab1-c1\", \"text\": \"\\\\textbf{Entry}\\\\refmark{[a]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [55.649443743475736, 368.81959823007617, 90.02617039837168, 39.08112823495202]}, {\"id\": \"1304-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [87.05392178941933, 428.1391678724141, 27.91509159639432, 31.404478045943563]}, {\"id\": \"1304-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [87.75179907932919, 478.3863327459238, 27.217214306484465, 34.19598720558304]}, {\"id\": \"1304-tab1-c4\", \"text\": \"3\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [85.65816720959963, 527.9356203295238, 30.008723466123882, 36.289619075312544]}, {\"id\": \"1304-tab1-c5\", \"text\": \"4\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [86.35604449950948, 581.6721716525828, 27.91509159639432, 34.893864495492835]}, {\"id\": \"1304-tab1-c6\", \"text\": \"5\\\\refmark{[d]}\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [78.67939431050104, 629.1278273664532, 41.174760104681624, 37.68537365513225]}, {\"id\": \"1304-tab1-c7\", \"text\": \"\\\\textbf{Solvent}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [323.63432306886114, 368.81959823007617, 105.37947077638853, 31.404478045943563]}, {\"id\": \"1304-tab1-c8\", \"text\": \"Toluene\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [325.03007764868084, 427.4412905825042, 98.40069787728999, 34.19598720558304]}, {\"id\": \"1304-tab1-c9\", \"text\": \"CH_3CN\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [332.7067278376893, 479.0842100358337, 87.93253852864211, 28.612968886304202]}, {\"id\": \"1304-tab1-c10\", \"text\": \"2-Me-THF\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [304.791636241295, 528.6334976194336, 131.20093050305326, 32.10235533585353]}, {\"id\": \"1304-tab1-c11\", \"text\": \"Et_2O\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [343.872764476247, 581.6721716525828, 68.39197441116607, 28.61296888630409]}, {\"id\": \"1304-tab1-c12\", \"text\": \"THF\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [343.1748871863372, 632.6172138160024, 61.413201512067474, 29.310846176214]}, {\"id\": \"1304-tab1-c13\", \"text\": \"\\\\textbf{Yield/%}\\\\refmark{[b]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [609.7640119319029, 368.81959823007617, 110.96248909566737, 38.383250945042164]}, {\"id\": \"1304-tab1-c14\", \"text\": \"92\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [643.959999137486, 430.23279974214364, 48.85141029369004, 30.00872346612391]}, {\"id\": \"1304-tab1-c15\", \"text\": \"trace\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [631.3982079191085, 477.68845545601397, 69.78772899098578, 32.80023262576333]}, {\"id\": \"1304-tab1-c16\", \"text\": \"46\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [641.1684899778464, 530.7271294891632, 51.64291945332957, 30.70660075603371]}, {\"id\": \"1304-tab1-c17\", \"text\": \"85\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [646.7515082971254, 573.9955214635744, 45.36202384414071, 43.2683919744112]}, {\"id\": \"1304-tab1-c18\", \"text\": \"98(85)\\\\refmark{[e]}\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [616.0449075410916, 629.1278273664532, 101.1922070369294, 35.591741785402746]}, {\"id\": \"1304-tab1-c19\", \"text\": \"\\\\textit{\\\\textbf{ee}}\\\\textbf{/%}\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [803.0760212369335, 362.5387026208874, 88.63041581855202, 40.476882814771784]}, {\"id\": \"1304-tab1-c20\", \"text\": \"89\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [826.1059718039588, 422.5561495531352, 44.66414655423091, 42.57051468450135]}, {\"id\": \"1304-tab1-c21\", \"text\": \"n.d.\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [811.4505487158518, 477.68845545601397, 69.08985170107587, 34.89386449549289]}, {\"id\": \"1304-tab1-c22\", \"text\": \"31\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [828.8974809635982, 525.1441111698844, 41.87263739459149, 39.77900552486187]}, {\"id\": \"1304-tab1-c23\", \"text\": \"87\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [825.4080945140489, 578.8806624929433, 46.05990113405062, 34.89386449549295]}, {\"id\": \"1304-tab1-c24\", \"text\": \"95\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [827.5017263837785, 629.1278273664532, 46.75777842396053, 31.404478045943506]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] All reactions were performed on a 0.20 mmol scale. [b] Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. [c] Determined by HPLC analysis on a chiral stationary phase. [d]MeOH:H_2O (1:1, 2.0 equiv) as proton source. [e] Isolated yield after flash chromatography on silica gel. n.d.= not detected.",
"unable_to_answer": false
},
{
"question": "How many molecular diagrams of benzene rings are there in the table?",
"answer": "There are 2 benzene rings in total.",
"unable_to_answer": false
},
{
"question": "What is the Yield value corresponding to an ee column value of 87?",
"answer": "85",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 3 and column 2 in the picture?",
"answer": "CH_3CN",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"CH_3CN\" in the picture?",
"answer": "Row 3, Column 2",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "6 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Solvent screening.",
"unable_to_answer": false
},
{
"question": "What solvent is used when the yield is the highest?",
"answer": "When the yield is the highest, the solvent used is THF.",
"unable_to_answer": false
}
]
} |
1305 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"S5\", \"text\": \"Additive screening.\", \"bbox\": [28.320512820512803, 20.05128205128205, 378.6153846153846, 46.00000000000001]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} All reactions were performed on a 0.20 mmol scale. \\\\mark{[b]} Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. \\\\mark{[c]} Determined by HPLC analysis on a chiral stationary phase. \\\\mark{[d]} Ar = 3,5-Ditrifluoromethylphenyl\", \"bbox\": [24.26061672173991, 609.6736309463961, 1062.7431461166304, 114.29709120592508]}]",
"reactions": "[{\"id\": \"1305-rea1\", \"reactants\": [{\"id\": \"1305-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [168.23099122151098, 150.28724513796627, 156.05948991578236, 225.29715093475622]}], \"conditions\": [{\"id\": \"1305-rea1-con1\", \"text\": \"Cu(CH_3CN)_4PF_6 (3.0 mol%)\", \"maps\": [], \"bbox\": [366.92313670320436, 81.89896945714172, 341.5445902611989, 29.631722442752405]}, {\"id\": \"1305-rea1-con2\", \"text\": \"(\\\\textit{R,R})-Ph-BPE(\\\\textbf{\\\\refiden{L1}}, 3.6 mol%)\", \"maps\": [], \"bbox\": [361.46466151638157, 109.9711275608019, 357.9200158216674, 29.63172244275242]}, {\"id\": \"1305-rea1-con3\", \"text\": \"LiO\\\\textit{t}Bu (40 mol%)\", \"maps\": [], \"bbox\": [423.8472350800709, 137.26350349491597, 223.7974826597353, 34.310415460029105]}, {\"id\": \"1305-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [361.46466151638157, 170.01435461585285, 347.0030654480217, 31.19128678184464]}, {\"id\": \"1305-rea1-con5\", \"text\": \"additive (3.6 mol%)\", \"maps\": [], \"bbox\": [419.94832423234027, 241.75431421409553, 235.49421520292708, 31.191286781844667]}, {\"id\": \"1305-rea1-con6\", \"text\": \"MeOH:H_2O (1:1, 2.0 equiv)\", \"maps\": [], \"bbox\": [374.7209583986656, 272.16581882639406, 325.94894687027653, 29.631722442752448]}, {\"id\": \"1305-rea1-con7\", \"text\": \"THF\", \"maps\": [], \"bbox\": [501.8254520346825, 302.5773234386926, 80.31756346324994, 22.613682916837377]}, {\"id\": \"1305-rea1-con8\", \"text\": \"0 °C to RT, 17 h\", \"maps\": [], \"bbox\": [407.47180951960246, 328.31013503371446, 243.2920368983883, 29.63172244275239]}], \"products\": [{\"id\": \"1305-rea1-pro-sub1\", \"text\": \"(\\\\textit{S})-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"2aa\", \"smiles\": \"[#smiles#][C@](C1=CC=CC=C1)([Si@@](C1=CC=CC=C1)(C)C)1NC1[#smiles#]\"}], \"bbox\": [762.7956675907944, 133.8020877524963, 185.73277320962836, 247.2773607820495]}], \"text\": \"\", \"bbox\": [153.94385482077033, 76.65354214953375, 798.9806279491112, 315.4160113086587]}]",
"substances": "[]",
"tables": "[{\"id\": \"1305-tab1\", \"text\": \"\", \"bbox\": [62.42930020093347, 415.8739068181041, 975.4789988859503, 182.13948583626023], \"data\": [{\"id\": \"1305-tab1-c1\", \"text\": \"\\\\textbf{Entry}\\\\refmark{[a]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [67.1236168461979, 425.262540108633, 109.84700949918786, 42.24884980737994]}, {\"id\": \"1305-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [99.0449700339961, 493.79956312949383, 48.82089311075015, 39.432259820221304]}, {\"id\": \"1305-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [98.1061067049432, 557.6422695050902, 47.882029781697284, 30.043626529692347]}, {\"id\": \"1305-tab1-c4\", \"text\": \"\\\\textbf{Additives}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [356.29352219448737, 432.7734467410561, 147.40154266130338, 37.55453316211555]}, {\"id\": \"1305-tab1-c5\", \"text\": \"NaPF_6\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [375.0707887755451, 493.79956312949383, 113.6024628153994, 40.37112314927418]}, {\"id\": \"1305-tab1-c6\", \"text\": \"NaBAr_4\\\\refmark{[d]}\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [365.6821554850162, 545.4370462274027, 140.82949935793317, 46.94316645264439]}, {\"id\": \"1305-tab1-c7\", \"text\": \"\\\\textbf{Yield/%}\\\\refmark{[b]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [690.3687201740037, 429.0179934248446, 143.6460893450918, 41.30998647832706]}, {\"id\": \"1305-tab1-c8\", \"text\": \"69\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [731.8388538156424, 493.79956312949383, 66.65929636275507, 39.432259820221304]}, {\"id\": \"1305-tab1-c9\", \"text\": \"61\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [735.5943071318541, 552.0090895307728, 47.88202978169727, 36.61566983306261]}, {\"id\": \"1305-tab1-c10\", \"text\": \"\\\\textit{\\\\textbf{ee}}\\\\textbf{/%}\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [909.2840230066382, 428.0791300957917, 107.96928284108208, 46.004303123591455]}, {\"id\": \"1305-tab1-c11\", \"text\": \"82\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [946.8385561687538, 497.55501644570535, 53.51520975601443, 36.61566983306267]}, {\"id\": \"1305-tab1-c12\", \"text\": \"84\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [947.7774194978067, 552.0090895307728, 47.882029781697156, 42.24884980738]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] All reactions were performed on a 0.20 mmol scale. [b] Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. [c] Determined by HPLC analysis on a chiral stationary phase. [d] Ar = 3,5-Ditrifluoromethylphenyl",
"unable_to_answer": false
},
{
"question": "How many benzene rings are present in the substance labeled as 1a in the table?",
"answer": "The substance labeled as 1a contains 1 benzene ring.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 2 and column 2 in the picture?",
"answer": "NaPF_6",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"NaPF_6\" in the picture?",
"answer": "Row 2, Column 2",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "3 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Additive screening.",
"unable_to_answer": false
},
{
"question": "What additive is used when the yield is at its highest?",
"answer": "When the yield is at its highest, the additive used is NaPF_6.",
"unable_to_answer": false
}
]
} |
1306 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"S6\", \"text\": \"Base screening.\", \"bbox\": [24.14583333333333, 6.041666666666667, 356.45833333333337, 47.125]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} All reactions were performed on a 0.20 mmol scale. \\\\mark{[b]} Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. \\\\mark{[c]} Determined by HPLC analysis on a chiral stationary phase.\", \"bbox\": [26.562499999999996, 647.6666666666666, 1057.2916666666667, 87]}]",
"reactions": "[{\"id\": \"1306-rea1\", \"reactants\": [{\"id\": \"1306-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [158.27083333333331, 138.95833333333334, 149.83333333333331, 218.70833333333334]}], \"conditions\": [{\"id\": \"1306-rea1-con1\", \"text\": \"Cu(CH_3CN)_4PF_6 (3.0 mol%)\", \"maps\": [], \"bbox\": [370.3919722049251, 79.65698579922159, 334.79957748364745, 31.754186730407795]}, {\"id\": \"1306-rea1-con2\", \"text\": \"(\\\\textit{R,R})-Ph-BPE(\\\\textbf{\\\\refiden{L1}}, 3.6 mol%)\", \"maps\": [], \"bbox\": [369.0113553905595, 110.72086412244661, 341.7026615554752, 33.13480354477335]}, {\"id\": \"1306-rea1-con3\", \"text\": \"Base (40 mol%)\", \"maps\": [], \"bbox\": [438.04219610883735, 143.16535926003718, 200.18943808300565, 28.30264469449392]}, {\"id\": \"1306-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [363.4888881330973, 171.4680039545311, 340.32204474110966, 32.444495137590565]}, {\"id\": \"1306-rea1-con5\", \"text\": \"MeOH:H_2O (1:1, 2.0 equiv)\", \"maps\": [], \"bbox\": [363.4888881330973, 240.67112815384115, 336.18019429801296, 33.134803544773376]}, {\"id\": \"1306-rea1-con6\", \"text\": \"THF\", \"maps\": [], \"bbox\": [500.1699527552874, 272.9433398103995, 72.48238275419175, 29.68326150885946]}, {\"id\": \"1306-rea1-con7\", \"text\": \"0 °C to RT, 17 h\", \"maps\": [], \"bbox\": [413.1910934502573, 302.62660131925895, 226.42115755595125, 32.44449513759059]}], \"products\": [{\"id\": \"1306-rea1-pro-sub1\", \"text\": \"(\\\\textit{S})-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"3aa\", \"smiles\": \"[#smiles#][C@](C1=CC=CC=C1)([Si@@](C1=CC=CC=C1)(C)C)1NC1[#smiles#]\"}], \"bbox\": [768.4791666666666, 132.91666666666666, 178.83333333333337, 230.79166666666666]}], \"text\": \"\", \"bbox\": [151.02083333333334, 60.416666666666664, 799.9166666666666, 314.16666666666663]}]",
"substances": "[]",
"tables": "[{\"id\": \"1306-tab1\", \"text\": \"\", \"bbox\": [55.46412150065106, 401.9729309082031, 981.6858215332031, 242.11526489257812], \"data\": [{\"id\": \"1306-tab1-c1\", \"text\": \"\\\\textbf{Entry}\\\\refmark{[a]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [69.89724384268682, 410.11125734481936, 111.90201265767281, 48.829969159711766]}, {\"id\": \"1306-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [103.46784763998866, 482.3389200602263, 37.63976789394448, 36.622476869783895]}, {\"id\": \"1306-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [101.43326559166734, 542.3590904857053, 36.622476869783824, 36.622476869783895]}, {\"id\": \"1306-tab1-c4\", \"text\": \"3\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [100.41597456750668, 600.3446788628631, 35.60518584562317, 32.5533127731411]}, {\"id\": \"1306-tab1-c5\", \"text\": \"\\\\textbf{Base}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [387.2920433808133, 415.19771246562266, 88.50431910197761, 42.7262230147478]}, {\"id\": \"1306-tab1-c6\", \"text\": \"KO\\\\textit{t}Bu\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [375.0845510908854, 480.30433801190503, 111.9020126576728, 36.62247686978384]}, {\"id\": \"1306-tab1-c7\", \"text\": \"NaO\\\\textit{t}Bu\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [374.0672607421875, 542.3590698242188, 120.04034423828125, 34.58795166015625]}, {\"id\": \"1306-tab1-c8\", \"text\": \"LiOMe\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [385.25746133249197, 598.3100968145418, 95.62535627110225, 37.63976789394451]}, {\"id\": \"1306-tab1-c9\", \"text\": \"\\\\textbf{Yield/%}\\\\refmark{[b]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [699.6003877981365, 416.2150034897833, 132.2478331408861, 36.62247686978384]}, {\"id\": \"1306-tab1-c10\", \"text\": \"98\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [741.3093197887237, 483.356211084387, 41.708931990587075, 32.55331277314116]}, {\"id\": \"1306-tab1-c11\", \"text\": \"98\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [740.2920287645629, 540.3245084373841, 49.847260183872436, 35.60518584562317]}, {\"id\": \"1306-tab1-c12\", \"text\": \"96\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [740.2920287645629, 601.3619698870237, 44.76080506306914, 32.553312773141215]}, {\"id\": \"1306-tab1-c13\", \"text\": \"\\\\textit{\\\\textbf{ee}}\\\\textbf{/%}\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [919.3352490168395, 418.2495855381046, 100.71181139190548, 42.7262230147478]}, {\"id\": \"1306-tab1-c14\", \"text\": \"94\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [945.7848156450167, 484.37350210854765, 51.881842232193776, 35.60518584562317]}, {\"id\": \"1306-tab1-c15\", \"text\": \"94\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [953.9231438383019, 540.3245084373841, 35.60518584562317, 35.60518584562317]}, {\"id\": \"1306-tab1-c16\", \"text\": \"95\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [947.819397693338, 598.3100968145418, 44.76080506306914, 34.58789482146244]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] All reactions were performed on a 0.20 mmol scale. [b] Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. [c] Determined by HPLC analysis on a chiral stationary phase.",
"unable_to_answer": false
},
{
"question": "How many molecular diagrams of benzene rings are there in the table?",
"answer": "There are 2 benzene rings in total.",
"unable_to_answer": false
},
{
"question": "What was the ee when LiOMe was used as the base?",
"answer": "95",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 2 and column 2 in the picture?",
"answer": "KOtBu",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"KOtBu\" in the picture?",
"answer": "Row 2, Column 2",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "4 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Base screening.",
"unable_to_answer": false
},
{
"question": "What is the substance marked in green in the table?",
"answer": "Unable to answer.",
"unable_to_answer": true
},
{
"question": "What is the base used when the yield is the lowest?",
"answer": "When the yield is the lowest, the base used is LiOMe.",
"unable_to_answer": false
}
]
} |
1307 | https://doi.org/10.1002 anie.202215032 | {
"title": "[{\"type\": \"Table\", \"index\": \"S7\", \"text\": \"McQuade's N-heterocyclic carbene/copper-catalyzed silylation of 2\\\\textit{H}-aziridines.\", \"bbox\": [20.71484034297727, 4.885637152408939, 1056.7661389628217, 85.957054365397]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} All reactions were performed outside the glove box on a 0.10 mmol scale. \\\\mark{[b]} Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. \\\\mark{[c]} Determined by HPLC analysis on a chiral stationary phase. \\\\mark{[d]} NaOMe was quickly weighed out outside the glovebox and then returned for storage.\", \"bbox\": [15.658543027365681, 617.9616866703141, 1065.614659265142, 131.46373020590124]}]",
"reactions": "[{\"id\": \"1307-rea1\", \"reactants\": [{\"id\": \"1307-rea1-rea-sub1\", \"text\": \"\\\\iden{1a}\", \"maps\": [{\"identifier\": \"1a\", \"smiles\": \"[#smiles#]N1CC=1C1C=CC=CC=1[#smiles#]\"}], \"bbox\": [28.24357731632851, 188.50115314584892, 149.0012078093402, 193.3845463057394]}], \"conditions\": [{\"id\": \"1307-rea1-con1\", \"text\": \"McQuade's NHC-copper(I)\", \"maps\": [], \"bbox\": [213.9977095123452, 125.95552231516845, 312.5503041647171, 31.878744992410162]}, {\"id\": \"1307-rea1-con2\", \"text\": \"complex(5.0 mol%)\", \"maps\": [], \"bbox\": [250.7275678731656, 156.44823491660426, 241.8626522250249, 29.106680210461434]}, {\"id\": \"1307-rea1-con3\", \"text\": \"NaOMe (1.5 equiv)\", \"maps\": [], \"bbox\": [255.57868124157585, 185.5549151270657, 232.16042548820445, 24.948583037538384]}, {\"id\": \"1307-rea1-con4\", \"text\": \"Me_2PhSiBpin (\\\\textbf{\\\\refiden{2a}}, 1.5 equiv)\", \"maps\": [], \"bbox\": [202.2164341890632, 209.81048196911692, 338.1919033977425, 33.26477738338451]}, {\"id\": \"1307-rea1-con5\", \"text\": \"Et_2O\", \"maps\": [], \"bbox\": [332.50347894065254, 265.2517776080911, 81.08289487199977, 31.878744992410134]}, {\"id\": \"1307-rea1-con6\", \"text\": \"0 °C to RT, 12 h\", \"maps\": [], \"bbox\": [266.6669403693707, 296.4375064050141, 212.75597201456344, 31.185728796922945]}], \"products\": [{\"id\": \"1307-rea1-pro-sub1\", \"text\": \"(\\\\textit{R})-\\\\iden{3aa}\", \"maps\": [{\"identifier\": \"3aa\", \"smiles\": \"[#smiles#][C@](C1=CC=CC=C1)([Si@@](C1=CC=CC=C1)(C)C)1NC1[#smiles#]\"}], \"bbox\": [566.1273700464998, 157.0597910195684, 183.87383091365382, 221.91669248199602]}], \"text\": \"\", \"bbox\": [21.978914671880023, 106.01158346464071, 731.8990364347774, 284.41672400315184]}]",
"substances": "[]",
"tables": "[{\"id\": \"1307-tab1\", \"text\": \"\", \"bbox\": [30.824589714533165, 423.5541941722391, 1009.8389508729392, 184.96587629310073], \"data\": [{\"id\": \"1307-tab1-c1\", \"text\": \"\\\\textbf{Entry}\\\\refmark{[a]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [44.83715610037413, 442.237616020027, 109.29801780955958, 45.77438352708049]}, {\"id\": \"1307-tab1-c2\", \"text\": \"1\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [76.59897324161366, 505.761250302506, 32.69598823362894, 42.03769915752298]}, {\"id\": \"1307-tab1-c3\", \"text\": \"2\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [83.13817088833946, 567.4165424002064, 28.02513277168194, 33.630159326018315]}, {\"id\": \"1307-tab1-c4\", \"text\": \"\\\\textbf{Base}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [379.27040717577864, 443.17178711241644, 101.82464907044437, 42.037699157522866]}, {\"id\": \"1307-tab1-c5\", \"text\": \"NaOMe stored in the glovebox\\\\refmark{[d]}\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [233.53971676303254, 502.9587370253379, 407.2985962817776, 44.840212434691125]}, {\"id\": \"1307-tab1-c6\", \"text\": \"NaOMe stored outside the glovebox\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [207.3829261761294, 565.5482002154275, 454.9413219936369, 38.3010147879653]}, {\"id\": \"1307-tab1-c7\", \"text\": \"\\\\textbf{Yield/%}\\\\refmark{[b]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [727.7162246370241, 438.50093165046945, 133.58646621168396, 45.77438352708043]}, {\"id\": \"1307-tab1-c8\", \"text\": \"95\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [766.9514105173788, 511.36627685684243, 57.91860772814266, 33.630159326018315]}, {\"id\": \"1307-tab1-c9\", \"text\": \"95\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [770.6880948869365, 563.6798580306487, 50.445238989027416, 37.366843695575994]}, {\"id\": \"1307-tab1-c10\", \"text\": \"\\\\textit{\\\\textbf{ee}}\\\\textbf{/%}\\\\refmark{[c]}\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [917.352956392072, 436.63258946569067, 107.42967562478066, 47.642725711859214]}, {\"id\": \"1307-tab1-c11\", \"text\": \"81\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [946.3122602561433, 510.432105764453, 61.655292097700226, 34.564330418407735]}, {\"id\": \"1307-tab1-c12\", \"text\": \"93\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [955.6539711800373, 564.6140291230381, 49.51106789663811, 35.498501510797155]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] All reactions were performed outside the glove box on a 0.10 mmol scale. [b] Yield was determined by ^1H NMR analysis with CH_2Br_2 as an internal standard. [c] Determined by HPLC analysis on a chiral stationary phase. [d] NaOMe was quickly weighed out outside the glovebox and then returned for storage.",
"unable_to_answer": false
},
{
"question": "How many molecular diagrams of benzene rings are there in the table?",
"answer": "There are a total of 3 benzene rings.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 1 and column 4 in the picture?",
"answer": "ee/%[c]",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"ee/%[c]\" in the picture?",
"answer": "Row 1, Column 4",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "3 rows × 4 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "McQuade's N-heterocyclic carbene/copper-catalyzed silylation of 2H-aziridines.",
"unable_to_answer": false
}
]
} |
1308 | https://doi.org/10.1002 anie.202215250 | {
"title": "[{\"type\": \"Table\", \"index\": \"1\", \"text\": \"Physical properties of DBMP containing polymers with data for PIM-1 and PIM-1-AO included for comparison.\", \"bbox\": [23.730889798986546, 11.61165727539183, 1411.4991619726002, 42.46077697820949]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]} BET surface area (\\\\textit{SA}_{BET}) calculated from N_2 adsorption isotherm obtained at 77 K. \\\\mark{[b]}CO_2 uptakes at 1 bar and 273 K.\\\\mark{[c]}Total free volume (\\\\textit{V}_{Total}) estimated from N_2 adsorption at \\\\textit{p/p_0}=0.98. \\\\mark{[d]}Young's modulus of membranes measured by atomic force microscopy (AFM). \\\\mark{[e]}From GPC analysis relative to polystyrene standards. \\\\mark{[f]}Not measured due to insolubility in an appropriate solvent for GPC. \\\\mark{[g]}Partially soluble in quinoline.\", \"bbox\": [31.690731253582218, 502.08737162738953, 1682.593929450369, 146.18539786710414]}]",
"reactions": "[]",
"substances": "[]",
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\"end_col\": \"1\", \"maps\": [], \"bbox\": [26.536108346741415, 240.21775395828325, 178.1242223633854, 32.18210740178813]}, {\"id\": \"1308-tab1-c5\", \"text\": \"PIM-DBMP_{0.5}\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [26.536108346741415, 273.14828246243854, 165.4010636231436, 35.17579181125677]}, {\"id\": \"1308-tab1-c6\", \"text\": \"PIM-DBMP_{0.75}\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [26.536108346741415, 310.5693375807968, 175.87895905628392, 32.93052850415529]}, {\"id\": \"1308-tab1-c7\", \"text\": \"PIM-DBMP_{0.9}\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [31.026634960944406, 344.99670828968647, 162.40737921367491, 32.930528504155234]}, {\"id\": \"1308-tab1-c8\", \"text\": \"PIM-DBMP\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"1\", \"end_col\": \"1\", 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"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a] BET surface area (SA_{BET}) calculated from N_2 adsorption isotherm obtained at 77 K. [b]CO_2 uptakes at 1 bar and 273 K.[c]Total free volume (V_{Total}) estimated from N_2 adsorption at p/p_0=0.98. [d]Young's modulus of membranes measured by atomic force microscopy (AFM). [e]From GPC analysis relative to polystyrene standards. [f]Not measured due to insolubility in an appropriate solvent for GPC. [g]Partially soluble in quinoline.",
"unable_to_answer": false
},
{
"question": "What is the sum of the V_{Total} values for PIM-1, PIM-DBMP_{0.1}, PIM-DBMP_{0.25}, and PIM-DBMP_{0.5}?",
"answer": "The sum is 0.57 + 0.66 + 0.62 + 0.67 = 2.52 mL g^{-1}.",
"unable_to_answer": false
},
{
"question": "What is the mean CO2 uptake for PIM-DBMP_{0.1}, PIM-DBMP_{0.25}, PIM-DBMP_{0.5}, PIM-DBMP_{0.75}, PIM-DBMP_{0.9}, and PIM-DBMP?",
"answer": "The mean CO2 uptake is (2.5 + 2.4 + 2.6 + 2.4 + 2.4 + 2.4) / 6 = 2.45 mmol g^{-1}.",
"unable_to_answer": false
},
{
"question": "Which polymer has the maximum Young's Modulus among those with available data?",
"answer": "PIM-DBMP_{0.75} has the maximum Young's Modulus with a value of 3150 MPa.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 5 and column 2 in the picture?",
"answer": "65000[e]",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"65000[e]\" in the picture?",
"answer": "Row 5, Column 2",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "10 rows × 8 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Physical properties of DBMP containing polymers with data for PIM-1 and PIM-1-AO included for comparison.",
"unable_to_answer": false
}
]
} |
1309 | https://doi.org/10.1002 anie.202215381 | {
"title": "[{\"type\": \"Table\", \"index\": \"1\", \"text\": \"Reaction optimization.\", \"bbox\": [11.296224186988844, 11.07528462521761, 345.03038321624683, 34.359872187510064]}]",
"annotations": "[{\"text\": \"Reactions were run on a 0.1 mmol scale in 1 mL of solvent[0.1 M] using 10 mol% of catalst. \\\\mark{[a]}Yield and selectivity of \\\\textbf{\\\\refiden{2a}} and \\\\textbf{\\\\refiden{3a}} was determined by ^1H NMR from the crude reaction mixture using mesitylene as an internal standard.\\\\mark{[b]}Atmospheric oxygen was used as the terminal oxidant. \\\\mark{[c]}The reaction was run without the addition of water and under an Ar atmosphere. \\\\mark{[d]}Reaction was run with 5 mol% catalyst and stopped after 3 h.\", \"bbox\": [18.407185628742514, 654.0153977758769, 1480.4636441402906, 128.8502994011975]}]",
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"qa": [
{
"question": "What are the annotations of this table?",
"answer": "Reactions were run on a 0.1 mmol scale in 1 mL of solvent[0.1 M] using 10 mol% of catalst. [a]Yield and selectivity of 2a and 3a was determined by ^1H NMR from the crude reaction mixture using mesitylene as an internal standard.[b]Atmospheric oxygen was used as the terminal oxidant. [c]The reaction was run without the addition of water and under an Ar atmosphere. [d]Reaction was run with 5 mol% catalyst and stopped after 3 h.",
"unable_to_answer": false
},
{
"question": "Which entry gives the highest yield, and what are the catalyst, oxidant, solvent, and yield?",
"answer": "Entries 8 and 12 both give the highest yield of 95%. The catalyst is PdCl2(MeCN)2, the oxidant is tBuONO (1.0), and the solvent is EtOH.",
"unable_to_answer": false
},
{
"question": "What is the sum of all reported numerical yields (excluding '-', '<1', and duplicates)?",
"answer": "The sum of all reported numerical yields is 13 + 11 + 88 + 44 + 18 + 95 + 19 + 36 + 95 = 419.",
"unable_to_answer": false
},
{
"question": "What is the mean (average) yield of all reported numerical yields (excluding '-', '<1', and duplicates)?",
"answer": "There are 9 numerical yields: 13, 11, 88, 44, 18, 95, 19, 36, 95. The mean yield is 419 / 9 ≈ 46.56%.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 1 and column 4 in the picture?",
"answer": "Solvent",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"Solvent\" in the picture?",
"answer": "Row 1, Column 4",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "13 rows × 6 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Reaction optimization.",
"unable_to_answer": false
},
{
"question": "What are the catalyst and solvent used when the yield is highest?",
"answer": "When the yield is highest, the catalyst used is PdCl_2 and the solvent is EtOH.",
"unable_to_answer": false
}
]
} |
1310 | https://doi.org/10.1002 anie.202215381 | {
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"qa": [
{
"question": "What are the annotations of this table?",
"answer": "Reactions were run on 0.20 mmol scale in 2 mL solvent (0.1 M) using 10 mol% catalyst, 11 mol% ligand,1.00 eg. tBuONO and 30.0 eq. water. aReaction run for 4h. bReaction run for 18 h. cReaction performed without addition of catalyst. dDetermined via ^1H-NMR analysis using mesitylene as internal standard.",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 13 and column 6 in the picture?",
"answer": "HFIP",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"HFIP\" in the picture?",
"answer": "Row 13, Column 6",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "14 rows × 10 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Optimization of reaction conditions for the asymmetric oxidative ring-expansion of methylenecyclobutanes.",
"unable_to_answer": false
},
{
"question": "What solvent is used when the yield is highest?",
"answer": "The solvent used when the yield is highest is dry EtOH.",
"unable_to_answer": false
}
]
} |
1311 | https://doi.org/10.1002 anie.202215381 | {
"title": "[{\"type\": \"Table\", \"index\": \"S6\", \"text\": \"Ligand screening conditions for the asymmetric oxidative ring-expansion of methylenecyclobutanes.\", \"bbox\": [17.786775825268425, 7.321999171267664, 617.8219117218144, 49.76898733314617]}]",
"annotations": "[{\"text\": \"Reactions were run on 0.20 mmol scale in 2 mL solvent (0.1M ) using 10 mol% catalyst, 11 mol% ligand, 11 mol% AgClO_4xH_2O, 1.00 eq. \\\\textit{t}BuONO and 30.0 eq. water. \\\\mark{a}Determined \\\\textit{via} ^1H-NMR analysis using mesitylene as internal standard. \\\\mark{b}The enantiomeric ratio was determined \\\\textit{via} HPLC using a chiral stationary phase (detailed conditions see corresponding entry in chapter 5.3).\", \"bbox\": [15.212517859760817, 688.6422740422687, 737.9539501121674, 80.66008291923697]}]",
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"qa": [
{
"question": "What are the annotations of this table?",
"answer": "Reactions were run on 0.20 mmol scale in 2 mL solvent (0.1M ) using 10 mol% catalyst, 11 mol% ligand, 11 mol% AgClO_4xH_2O, 1.00 eq. tBuONO and 30.0 eq. water. aDetermined via ^1H-NMR analysis using mesitylene as internal standard. bThe enantiomeric ratio was determined via HPLC using a chiral stationary phase (detailed conditions see corresponding entry in chapter 5.3).",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 14 and column 3 in the picture?",
"answer": "47%",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"47%\" in the picture?",
"answer": "Row 14, Column 3",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "15 rows × 5 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Ligand screening conditions for the asymmetric oxidative ring-expansion of methylenecyclobutanes.",
"unable_to_answer": false
}
]
} |
1314 | https://doi.org/10.1002 anie.202217186 | {
"title": "[{\"type\": \"Table\", \"index\": \"S2\", \"text\": \"Composition (measured by ICP) and mean diameter of the Mn_3O_4:M nanoparticles (from TEM).\", \"bbox\": [6.015242715838054, 8.086918941381594, 1029.6967615580297, 41.906263551780285]}]",
"annotations": "[{\"text\": \"\\\\mark{[a]}Initial molar ratio between substituent\\nand Mn precursor was 0.025 to 1, except for Mn_3O_4:Sr (0.05) where the ratio was 0.05 to 1.\", \"bbox\": [6.679515880838354, 658.7774978935016, 1256.6608793112493, 37.487938033928344]}]",
"reactions": "[]",
"substances": "[]",
"tables": "[{\"id\": \"1314-tab1\", \"text\": \"\", \"bbox\": [19.718798675248205, 67.1200410971547, 1264.8104310577553, 565.5788912075272], \"data\": [{\"id\": \"1314-tab1-c1\", \"text\": \"Mn_3O_4\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"1\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [189.92257622104887, 169.48940637773933, 84.21167239765589, 38.390615357754854]}, {\"id\": \"1314-tab1-c2\", \"text\": \"M in Mn_3O_4:M\", \"start_row\": \"3\", \"end_row\": \"8\", \"start_col\": \"1\", \"end_col\": \"1\", \"maps\": [], \"bbox\": [67.32028846563813, 399.83309852426856, 156.03927532506822, 50.77468482799844]}, {\"id\": \"1314-tab1-c3\", \"text\": \"Sr (0.05)\\\\refmark{[a]}\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [300.06933933969293, 230.9488003053227, 120.49249707091366, 48.70973285845449]}, {\"id\": \"1314-tab1-c4\", \"text\": \"Sr\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [339.3789483131825, 301.8770078009669, 43.58239255756456, 38.45505225667455]}, {\"id\": \"1314-tab1-c5\", \"text\": \"Ca\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [336.8152781627375, 378.78711231431606, 46.14606270800954, 29.90948508852466]}, {\"id\": \"1314-tab1-c6\", \"text\": \"Mg\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [338.52439159636754, 447.1516496595153, 36.74593882304458, 31.618598522154684]}, {\"id\": \"1314-tab1-c7\", \"text\": \"Zn\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [340.2335050299975, 507.8251765533796, 40.16416569030457, 36.74593882304464]}, {\"id\": \"1314-tab1-c8\", \"text\": \"Cu\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"2\", \"end_col\": \"2\", \"maps\": [], \"bbox\": [341.94261846362747, 578.7533840490238, 39.30960897348956, 30.76404180533973]}, {\"id\": \"1314-tab1-c9\", \"text\": \"Atomic composition (M_xMn_{3-x}O_4)\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [520.5449722779605, 81.40137486269937, 207.6572821860426, 56.40074330978938]}, {\"id\": \"1314-tab1-c10\", \"text\": \"---\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [603.4369738090145, 177.9662838627933, 43.5823925575645, 26.4912582212647]}, {\"id\": \"1314-tab1-c11\", \"text\": \"Sr_{0.15}Mn_{2.85}O_4\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": [554.72724095056, 240.3489241902876, 145.27464185854842, 35.8913821062296]}, {\"id\": \"1314-tab1-c12\", \"text\": \"Sr_{0.06}Mn_{2.94}O_4\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"3\", \"end_col\": \"3\", \"maps\": [], \"bbox\": 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308.71346153548683, 47.00061942482455, 31.618598522154628]}, {\"id\": \"1314-tab1-c21\", \"text\": \"2.7\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [912.786505296041, 372.8052152966111, 41.01872240711964, 35.89138210622963]}, {\"id\": \"1314-tab1-c22\", \"text\": \"2.3\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [911.0773918624111, 445.4425362258853, 48.70973285845446, 35.036825389414616]}, {\"id\": \"1314-tab1-c23\", \"text\": \"2.7\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [916.2047321633011, 510.3888467038246, 33.327711955784594, 29.90948508852466]}, {\"id\": \"1314-tab1-c24\", \"text\": \"1.0\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"4\", \"end_col\": \"4\", \"maps\": [], \"bbox\": [916.2047321633011, 578.7533840490238, 41.018722407119526, 42.72783584074955]}, {\"id\": \"1314-tab1-c25\", \"text\": \"\\\\overline{\\\\textit{d}} (nm)\", \"start_row\": \"1\", \"end_row\": \"1\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1125.5711277829737, 78.83770471225439, 82.03744481423905, 49.564289575269456]}, {\"id\": \"1314-tab1-c26\", \"text\": \"3.7\", \"start_row\": \"2\", \"end_row\": \"2\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1148.6441591369785, 166.85704654419843, 42.72783584074955, 37.600495539859565]}, {\"id\": \"1314-tab1-c27\", \"text\": \"3.9\", \"start_row\": \"3\", \"end_row\": \"3\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1148.6441591369785, 237.7852540398426, 40.16416569030457, 34.18226867259963]}, {\"id\": \"1314-tab1-c28\", \"text\": \"4.5\", \"start_row\": \"4\", \"end_row\": \"4\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1142.6622621192735, 304.4406779514119, 50.41884629208448, 36.74593882304458]}, {\"id\": \"1314-tab1-c29\", \"text\": \"4.3\", \"start_row\": \"5\", \"end_row\": \"5\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1141.8077054024584, 370.2415451461661, 51.27340300889955, 36.74593882304464]}, {\"id\": \"1314-tab1-c30\", \"text\": \"4.1\", \"start_row\": \"6\", \"end_row\": \"6\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1144.3713755529034, 443.73342279225534, 50.41884629208448, 37.60049553985954]}, {\"id\": \"1314-tab1-c31\", \"text\": \"3.4\", \"start_row\": \"7\", \"end_row\": \"7\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1152.0623860042383, 511.2434034206396, 43.58239255756462, 36.74593882304458]}, {\"id\": \"1314-tab1-c32\", \"text\": \"4.9\", \"start_row\": \"8\", \"end_row\": \"8\", \"start_col\": \"5\", \"end_col\": \"5\", \"maps\": [], \"bbox\": [1146.9350457033484, 578.7533840490238, 43.58239255756462, 31.618598522154684]}]}]",
"qa": [
{
"question": "What are the annotations of this table?",
"answer": "[a]Initial molar ratio between substituent and Mn precursor was 0.025 to 1, except for Mn_3O_4:Sr (0.05) where the ratio was 0.05 to 1.",
"unable_to_answer": false
},
{
"question": "What is the atomic composition of the nanoparticle when Sr is doped with an initial molar ratio of 0.05?",
"answer": "Sr0.15Mn2.85O4",
"unable_to_answer": false
},
{
"question": "What is the content of the cell at row 7 and column 2 in the picture?",
"answer": "Zn",
"unable_to_answer": false
},
{
"question": "What is the position of the cell with value \"Zn\" in the picture?",
"answer": "Row 7, Column 2",
"unable_to_answer": false
},
{
"question": "What is the size of the table in the picture?",
"answer": "8 rows × 5 columns",
"unable_to_answer": false
},
{
"question": "What is the title of this table?",
"answer": "Composition (measured by ICP) and mean diameter of the Mn_3O_4:M nanoparticles (from TEM).",
"unable_to_answer": false
}
]
} |
End of preview. Expand
in Data Studio
The dataset is sourced from Benchmarking Multimodal LLMs on Recognition and Understanding over Chemical Tables, which is currently under review at NeurIPS 2025. This dataset represents only a portion of the complete collection, which will be made fully available upon the publication of the paper.
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